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- W4310255591 endingPage "107067" @default.
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- W4310255591 abstract "Due to 2nd-order Jahn-Teller effect, some M cations such as Ti4+, Sn4+, In3+, Nb5+, Cu2+ and W6+ are allowed to enter the MO6 octahedral site while maintaining the high-symmetry structure of MTe3O8. Therefore, the series of MTe3O8 compounds when M = Sn, Ti, In0·5Nb0·45V0.05 and In0·4Cu0·1Nb0·4W0.1 were successfully synthesized. Rietveld refinement is utilized to visualize the crystal structures. M − O bonds are expanded because of the larger M cations while the O-M-O angles are distorted slightly. As a result of stereoactive 5s2 lone-pair electron of Te4+ in TeO4E unit, the structure is flexible as reflected by the small variation of Te–O bond lengths and O–Te–O angles. XANES reveal that the local structures of all compounds are preserved. However, different M cations affect their color and electronic band structures, which can be explained differently by the simple band-to-band transition, the VB-V 3d electronic transition and the d-d electronic transition." @default.
- W4310255591 created "2022-11-30" @default.
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- W4310255591 date "2023-01-01" @default.
- W4310255591 modified "2023-10-17" @default.
- W4310255591 title "Effects of M cations on crystal structure and optical properties of MTe3O8 tellurites" @default.
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- W4310255591 doi "https://doi.org/10.1016/j.solidstatesciences.2022.107067" @default.
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