FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310258747> ?p ?o ?g. }

• W4310258747 endingPage "17089" @default.
• W4310258747 startingPage "17081" @default.
• W4310258747 abstract "In this contribution, we describe a novel modeling approach to predicting retention times (tr) in comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry (GC × GC–ToF-MS) with a particular emphasis on the second-dimension (2D) retention time predictions (2tr). This approach is referred to as a “top-down” approach in that it breaks down the complete GC × GC separation into two independent one-dimensional gas chromatography separations (1D-GC). In this regard, both dimensions, that is, first dimension (1D) and second dimension (2D) are treated separately, and the cryogenic modulator is simply considered as a second consecutive injection device. Separate 1D-GC tr predictions are performed on both dimensions using the same flow rate as the one deployed in the conventional GC × GC system. The separate tr predictions are then combined to account for the two-dimensional separation. This model was applied to 24 analytes from 2 standard mixtures (Grob Test Mix and Fragrance Materials Test Mix) and assessed across 9 GC × GC chromatographic conditions. The experimental and predicted chromatographic retention space occupations were assessed by using the convex hull approach defined by the Delaunay triangulation. The predicted percentage of space occupation corresponded favorably with the experimental values. Furthermore, the top-down approach enabled an accurate prediction of the 2tr of all investigated analytes, providing an average 2tr modeling error of 0.26 ± 0.01 s." @default.
• W4310258747 created "2022-11-30" @default.
• W4310258747 creator A5041292155 @default.
• W4310258747 creator A5080991947 @default.
• W4310258747 creator A5083152430 @default.
• W4310258747 creator A5084759946 @default.
• W4310258747 date "2022-11-29" @default.
• W4310258747 modified "2023-10-03" @default.
• W4310258747 title "Top-Down Approach to Retention Time Prediction in Comprehensive Two-Dimensional Gas Chromatography–Mass Spectrometry" @default.
• W4310258747 cites W1964663464 @default.
• W4310258747 cites W1986743685 @default.
• W4310258747 cites W1993253107 @default.
• W4310258747 cites W2000482786 @default.
• W4310258747 cites W2004988621 @default.
• W4310258747 cites W2048389369 @default.
• W4310258747 cites W2060322865 @default.
• W4310258747 cites W2063971111 @default.
• W4310258747 cites W2069459485 @default.
• W4310258747 cites W2070300718 @default.
• W4310258747 cites W2074750486 @default.
• W4310258747 cites W2074771664 @default.
• W4310258747 cites W2079603221 @default.
• W4310258747 cites W2084803499 @default.
• W4310258747 cites W2089763991 @default.
• W4310258747 cites W2090026947 @default.
• W4310258747 cites W2095439146 @default.
• W4310258747 cites W2147105060 @default.
• W4310258747 cites W2333011007 @default.
• W4310258747 cites W2489008926 @default.
• W4310258747 cites W2568296716 @default.
• W4310258747 cites W2590221515 @default.
• W4310258747 cites W2766198875 @default.
• W4310258747 cites W2899234087 @default.
• W4310258747 cites W2914651689 @default.
• W4310258747 cites W2936391230 @default.
• W4310258747 cites W2964468913 @default.
• W4310258747 cites W2988158581 @default.
• W4310258747 cites W2991379776 @default.
• W4310258747 cites W3105907925 @default.
• W4310258747 cites W3168872709 @default.
• W4310258747 cites W4220794413 @default.
• W4310258747 cites W85618247 @default.
• W4310258747 doi "https://doi.org/10.1021/acs.analchem.2c03107" @default.
• W4310258747 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36444996" @default.
• W4310258747 hasPublicationYear "2022" @default.
• W4310258747 type Work @default.
• W4310258747 citedByCount "3" @default.
• W4310258747 countsByYear W43102587472023 @default.
• W4310258747 crossrefType "journal-article" @default.
• W4310258747 hasAuthorship W4310258747A5041292155 @default.
• W4310258747 hasAuthorship W4310258747A5080991947 @default.
• W4310258747 hasAuthorship W4310258747A5083152430 @default.
• W4310258747 hasAuthorship W4310258747A5084759946 @default.
• W4310258747 hasConcept C10390740 @default.
• W4310258747 hasConcept C112680207 @default.
• W4310258747 hasConcept C113196181 @default.
• W4310258747 hasConcept C123460561 @default.
• W4310258747 hasConcept C137777109 @default.
• W4310258747 hasConcept C145148216 @default.
• W4310258747 hasConcept C162356407 @default.
• W4310258747 hasConcept C16291436 @default.
• W4310258747 hasConcept C178790620 @default.
• W4310258747 hasConcept C185592680 @default.
• W4310258747 hasConcept C198291218 @default.
• W4310258747 hasConcept C202444582 @default.
• W4310258747 hasConcept C205345274 @default.
• W4310258747 hasConcept C206194317 @default.
• W4310258747 hasConcept C2524010 @default.
• W4310258747 hasConcept C3020018676 @default.
• W4310258747 hasConcept C33676613 @default.
• W4310258747 hasConcept C33923547 @default.
• W4310258747 hasConcept C43617362 @default.
• W4310258747 hasConcept C72850032 @default.
• W4310258747 hasConceptScore W4310258747C10390740 @default.
• W4310258747 hasConceptScore W4310258747C112680207 @default.
• W4310258747 hasConceptScore W4310258747C113196181 @default.
• W4310258747 hasConceptScore W4310258747C123460561 @default.
• W4310258747 hasConceptScore W4310258747C137777109 @default.
• W4310258747 hasConceptScore W4310258747C145148216 @default.
• W4310258747 hasConceptScore W4310258747C162356407 @default.
• W4310258747 hasConceptScore W4310258747C16291436 @default.
• W4310258747 hasConceptScore W4310258747C178790620 @default.
• W4310258747 hasConceptScore W4310258747C185592680 @default.
• W4310258747 hasConceptScore W4310258747C198291218 @default.
• W4310258747 hasConceptScore W4310258747C202444582 @default.
• W4310258747 hasConceptScore W4310258747C205345274 @default.
• W4310258747 hasConceptScore W4310258747C206194317 @default.
• W4310258747 hasConceptScore W4310258747C2524010 @default.
• W4310258747 hasConceptScore W4310258747C3020018676 @default.
• W4310258747 hasConceptScore W4310258747C33676613 @default.
• W4310258747 hasConceptScore W4310258747C33923547 @default.
• W4310258747 hasConceptScore W4310258747C43617362 @default.
• W4310258747 hasConceptScore W4310258747C72850032 @default.
• W4310258747 hasFunder F4320321390 @default.
• W4310258747 hasFunder F4320321730 @default.
• W4310258747 hasIssue "49" @default.
• W4310258747 hasLocation W43102587471 @default.
• W4310258747 hasLocation W43102587472 @default.

• next