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- W4310287130 abstract "Abstract Over the last decade, cobalt‐catalyzed CH bond functionalization has proven to be a valuable tool for the synthesis of complex molecules. In particular, bidentate chelation‐assisted CH bond functionalization methodology has witnessed tremendous growth in a relatively short time, having numerous novel transformations developed for various substrate groups, utilizing a broad range of directing groups. Despite the progress made in this field, the understanding of mechanistic aspects for the transformations is not very well established as the majority of the proposed mechanisms rely on well‐studied mechanistic aspects of precious transition metals. As a consequence, only a few studies actually explain the catalyst's mode of action in depth based on meaningful mechanistic experiments and theoretical calculations. In this article, we summarize the current understanding of the mechanisms for cobalt‐catalyzed, bidentate chelation‐assisted CH bond functionalization with different coupling partners that are based either on experimental evidence or theoretical calculations." @default.
- W4310287130 created "2022-11-30" @default.
- W4310287130 creator A5004209508 @default.
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- W4310287130 date "2022-11-29" @default.
- W4310287130 modified "2023-10-02" @default.
- W4310287130 title "Mechanistic Studies on Cobalt‐Catalyzed, Bidentate Chelation‐Assisted CH Bond Functionalization" @default.
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- W4310287130 doi "https://doi.org/10.1002/9783527834242.chf0236" @default.
- W4310287130 hasPublicationYear "2022" @default.
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