FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310287163> ?p ?o ?g. }

• W4310287163 endingPage "46" @default.
• W4310287163 startingPage "1" @default.
• W4310287163 abstract "Abstract Transition metal‐catalyzed directed aromatic ortho CH activation offers many possibilities for the functionalization of various substrates having different directing groups. However, the reactivity of the substrate is determined by electronic and steric factors. Herein, we present and discuss a recently developed model which considers only the steric properties of the substrates to assess their reactivity in ortho CH activation in the presence of ortho substituents. Dihedral angle between the directing group and the aromatic ring influences the coordination and the CH activation elementary step, thus determine reactivities and the stability of metal‐complex intermediates. The presentation of the theoretical model is followed by several literature examples from substrates having borderline reactivities, to explore and describe the most interesting region of reactivity. The most commonly used directing groups are discussed taking into consideration their key structural elements, and reactivity trends are presented with the help of complex formation and reactions of each substrate group. The lack of transformation is also discussed by showing representatives of unreactive substrates." @default.
• W4310287163 created "2022-11-30" @default.
• W4310287163 creator A5000266465 @default.
• W4310287163 creator A5012453189 @default.
• W4310287163 creator A5021536267 @default.
• W4310287163 date "2022-11-29" @default.
• W4310287163 modified "2023-10-16" @default.
• W4310287163 title "Steric Effects in <i>ortho</i> CH Activation of Aromatic Systems" @default.
• W4310287163 cites W1499090585 @default.
• W4310287163 cites W1968589663 @default.
• W4310287163 cites W1970968806 @default.
• W4310287163 cites W1976900023 @default.
• W4310287163 cites W1981442284 @default.
• W4310287163 cites W1984291726 @default.
• W4310287163 cites W1990514145 @default.
• W4310287163 cites W1993216537 @default.
• W4310287163 cites W1998861051 @default.
• W4310287163 cites W2004370627 @default.
• W4310287163 cites W2009737380 @default.
• W4310287163 cites W2013528775 @default.
• W4310287163 cites W2015431308 @default.
• W4310287163 cites W2017772742 @default.
• W4310287163 cites W2035793944 @default.
• W4310287163 cites W2045423362 @default.
• W4310287163 cites W2046361452 @default.
• W4310287163 cites W2051779046 @default.
• W4310287163 cites W2056067304 @default.
• W4310287163 cites W2061767335 @default.
• W4310287163 cites W2070080006 @default.
• W4310287163 cites W2071053863 @default.
• W4310287163 cites W2074578669 @default.
• W4310287163 cites W2081750775 @default.
• W4310287163 cites W2093731515 @default.
• W4310287163 cites W2102005773 @default.
• W4310287163 cites W2109551814 @default.
• W4310287163 cites W2141963830 @default.
• W4310287163 cites W2146822783 @default.
• W4310287163 cites W2162828246 @default.
• W4310287163 cites W2167192463 @default.
• W4310287163 cites W2183767990 @default.
• W4310287163 cites W2262102429 @default.
• W4310287163 cites W2315337362 @default.
• W4310287163 cites W2315971711 @default.
• W4310287163 cites W2326587253 @default.
• W4310287163 cites W2461688213 @default.
• W4310287163 cites W2466517671 @default.
• W4310287163 cites W2476805074 @default.
• W4310287163 cites W2516081743 @default.
• W4310287163 cites W2561579115 @default.
• W4310287163 cites W2563038574 @default.
• W4310287163 cites W2595112198 @default.
• W4310287163 cites W2601909871 @default.
• W4310287163 cites W2602284105 @default.
• W4310287163 cites W2745169597 @default.
• W4310287163 cites W2745194449 @default.
• W4310287163 cites W2799104697 @default.
• W4310287163 cites W2805951914 @default.
• W4310287163 cites W2806954513 @default.
• W4310287163 cites W2878025096 @default.
• W4310287163 cites W2891099781 @default.
• W4310287163 cites W2910024781 @default.
• W4310287163 cites W2943297759 @default.
• W4310287163 cites W2950144921 @default.
• W4310287163 cites W2950988139 @default.
• W4310287163 cites W2951039099 @default.
• W4310287163 cites W2953128749 @default.
• W4310287163 cites W2991616561 @default.
• W4310287163 cites W3001970521 @default.
• W4310287163 cites W3008716853 @default.
• W4310287163 cites W3016650167 @default.
• W4310287163 cites W3039350781 @default.
• W4310287163 cites W3134044460 @default.
• W4310287163 doi "https://doi.org/10.1002/9783527834242.chf0080" @default.
• W4310287163 hasPublicationYear "2022" @default.
• W4310287163 type Work @default.
• W4310287163 citedByCount "0" @default.
• W4310287163 crossrefType "other" @default.
• W4310287163 hasAuthorship W4310287163A5000266465 @default.
• W4310287163 hasAuthorship W4310287163A5012453189 @default.
• W4310287163 hasAuthorship W4310287163A5021536267 @default.
• W4310287163 hasConcept C111368507 @default.
• W4310287163 hasConcept C112887158 @default.
• W4310287163 hasConcept C127313418 @default.
• W4310287163 hasConcept C142724271 @default.
• W4310287163 hasConcept C147597530 @default.
• W4310287163 hasConcept C178790620 @default.
• W4310287163 hasConcept C185592680 @default.
• W4310287163 hasConcept C201194858 @default.
• W4310287163 hasConcept C204787440 @default.
• W4310287163 hasConcept C21951064 @default.
• W4310287163 hasConcept C2776910235 @default.
• W4310287163 hasConcept C2777289219 @default.
• W4310287163 hasConcept C2780378348 @default.
• W4310287163 hasConcept C32909587 @default.
• W4310287163 hasConcept C41339378 @default.
• W4310287163 hasConcept C71240020 @default.
• W4310287163 hasConcept C71924100 @default.
• W4310287163 hasConcept C89025888 @default.

• next