Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310288045> ?p ?o ?g. }
- W4310288045 abstract "The hydrodemethylation (HDM) of toluene to benzene is an industrial process performed at elevated temperatures (≈500 °C and higher). Here, it was reported that heating graphite-supported potassium hydride (KH/C) with toluene under H2 atmosphere provided benzene already at 125-250 °C. Depending on the H2 pressure, the reaction was either substoichiometric ( ≤11 bar) or catalytic ( ≥50 bar) with respect to KH, indicating that KH may serve as a radical chain initiator. At 250 °C, the selectivity to benzene was 98 and 63 % when using 6 and 80 bar of H2 , respectively, owing to the competing formation of cyclohexane and methylcyclohexane at high H2 pressure. The used KH/C material was amenable to recycling without a notable loss in the yield of benzene." @default.
- W4310288045 created "2022-11-30" @default.
- W4310288045 creator A5007422032 @default.
- W4310288045 creator A5076447968 @default.
- W4310288045 date "2022-12-12" @default.
- W4310288045 modified "2023-10-18" @default.
- W4310288045 title "Production of Benzene by the Hydrodemethylation of Toluene with Carbon‐Supported Potassium Hydride" @default.
- W4310288045 cites W1970586564 @default.
- W4310288045 cites W1985736209 @default.
- W4310288045 cites W1986149718 @default.
- W4310288045 cites W1987606859 @default.
- W4310288045 cites W1997920835 @default.
- W4310288045 cites W2000918596 @default.
- W4310288045 cites W2016638977 @default.
- W4310288045 cites W2017751578 @default.
- W4310288045 cites W2021201778 @default.
- W4310288045 cites W2025508392 @default.
- W4310288045 cites W2027575212 @default.
- W4310288045 cites W2029561965 @default.
- W4310288045 cites W2033424645 @default.
- W4310288045 cites W2033884403 @default.
- W4310288045 cites W2039078617 @default.
- W4310288045 cites W2046629335 @default.
- W4310288045 cites W2047284365 @default.
- W4310288045 cites W2049616780 @default.
- W4310288045 cites W2052539558 @default.
- W4310288045 cites W2055262441 @default.
- W4310288045 cites W2098155996 @default.
- W4310288045 cites W2283892304 @default.
- W4310288045 cites W2312496749 @default.
- W4310288045 cites W2321721470 @default.
- W4310288045 cites W2460912765 @default.
- W4310288045 cites W2589105796 @default.
- W4310288045 cites W2887648920 @default.
- W4310288045 cites W3005278508 @default.
- W4310288045 cites W3174052312 @default.
- W4310288045 cites W4220902042 @default.
- W4310288045 cites W4281724756 @default.
- W4310288045 cites W4310288045 @default.
- W4310288045 cites W81577056 @default.
- W4310288045 doi "https://doi.org/10.1002/cssc.202202029" @default.
- W4310288045 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36445808" @default.
- W4310288045 hasPublicationYear "2022" @default.
- W4310288045 type Work @default.
- W4310288045 citedByCount "1" @default.
- W4310288045 countsByYear W43102880452022 @default.
- W4310288045 crossrefType "journal-article" @default.
- W4310288045 hasAuthorship W4310288045A5007422032 @default.
- W4310288045 hasAuthorship W4310288045A5076447968 @default.
- W4310288045 hasBestOaLocation W43102880451 @default.
- W4310288045 hasConcept C104779481 @default.
- W4310288045 hasConcept C118792377 @default.
- W4310288045 hasConcept C121332964 @default.
- W4310288045 hasConcept C134121241 @default.
- W4310288045 hasConcept C140205800 @default.
- W4310288045 hasConcept C153294291 @default.
- W4310288045 hasConcept C159985019 @default.
- W4310288045 hasConcept C161790260 @default.
- W4310288045 hasConcept C178790620 @default.
- W4310288045 hasConcept C179104552 @default.
- W4310288045 hasConcept C185592680 @default.
- W4310288045 hasConcept C188721877 @default.
- W4310288045 hasConcept C191897082 @default.
- W4310288045 hasConcept C192562407 @default.
- W4310288045 hasConcept C2776504022 @default.
- W4310288045 hasConcept C2777691172 @default.
- W4310288045 hasConcept C2777961443 @default.
- W4310288045 hasConcept C2778142098 @default.
- W4310288045 hasConcept C2778237882 @default.
- W4310288045 hasConcept C2779698641 @default.
- W4310288045 hasConcept C512968161 @default.
- W4310288045 hasConcept C75473681 @default.
- W4310288045 hasConceptScore W4310288045C104779481 @default.
- W4310288045 hasConceptScore W4310288045C118792377 @default.
- W4310288045 hasConceptScore W4310288045C121332964 @default.
- W4310288045 hasConceptScore W4310288045C134121241 @default.
- W4310288045 hasConceptScore W4310288045C140205800 @default.
- W4310288045 hasConceptScore W4310288045C153294291 @default.
- W4310288045 hasConceptScore W4310288045C159985019 @default.
- W4310288045 hasConceptScore W4310288045C161790260 @default.
- W4310288045 hasConceptScore W4310288045C178790620 @default.
- W4310288045 hasConceptScore W4310288045C179104552 @default.
- W4310288045 hasConceptScore W4310288045C185592680 @default.
- W4310288045 hasConceptScore W4310288045C188721877 @default.
- W4310288045 hasConceptScore W4310288045C191897082 @default.
- W4310288045 hasConceptScore W4310288045C192562407 @default.
- W4310288045 hasConceptScore W4310288045C2776504022 @default.
- W4310288045 hasConceptScore W4310288045C2777691172 @default.
- W4310288045 hasConceptScore W4310288045C2777961443 @default.
- W4310288045 hasConceptScore W4310288045C2778142098 @default.
- W4310288045 hasConceptScore W4310288045C2778237882 @default.
- W4310288045 hasConceptScore W4310288045C2779698641 @default.
- W4310288045 hasConceptScore W4310288045C512968161 @default.
- W4310288045 hasConceptScore W4310288045C75473681 @default.
- W4310288045 hasIssue "2" @default.
- W4310288045 hasLocation W43102880451 @default.
- W4310288045 hasLocation W43102880452 @default.
- W4310288045 hasLocation W43102880453 @default.
- W4310288045 hasLocation W43102880454 @default.
- W4310288045 hasOpenAccess W4310288045 @default.