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• W4310330140 endingPage "32479" @default.
• W4310330140 startingPage "32475" @default.
• W4310330140 abstract "Here, we report the crystal structures, phase transitions, and thermal, dielectric, and conducting properties of an ion-pair compound [C4-bmim][Ni(mnt)2] (1). 1 undergoes a three-step phase transition with four phases before melting. A two-step dielectric constant bistability is also realized by the structural phase transition in 1 occurring among phases I, II, and III, which is due to the in-plane oscillations of the alkyl chain and crystal-to-mesophase transition, respectively. Moreover, 1 exhibits rare temperature-dependent conducting properties accompanying structural phase transitions, and conductivity is very high with 0.00186 S cm-1 at 413 K. The conduction properties of phase III (mesophase) arise from the dipole molecular motion." @default.
• W4310330140 created "2022-12-08" @default.
• W4310330140 creator A5003730019 @default.
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• W4310330140 date "2022-01-01" @default.
• W4310330140 modified "2023-09-30" @default.
• W4310330140 title "Multi-step phase transition crystal with dielectric constant bistability and temperature-dependent conductivity" @default.
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• W4310330140 doi "https://doi.org/10.1039/d2ra05947a" @default.
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