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- W4310331856 endingPage "32060" @default.
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- W4310331856 abstract "Catalytic asymmetric α-regioselective Michael additions of vinylogous α-ketoester enolate are described herein. With 0.1-1.0 mol% loadings of a chiral bifunctional organocatalyst, the addition of a deconjugated α-keto ester to a series of nitroolefins, including the challenging β-alkylnitroalkenes, efficiently proceed, providing the Rauhut-Currier type products after isomerization of the terminal double bond in good yields (60-88%) with excellent regio- and enantioselectivities (94-99% ee, TON up to 160 with 0.5 mol% of the catalyst)." @default.
- W4310331856 created "2022-12-08" @default.
- W4310331856 creator A5029698486 @default.
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- W4310331856 creator A5083700261 @default.
- W4310331856 creator A5090544920 @default.
- W4310331856 creator A5090632692 @default.
- W4310331856 date "2022-01-01" @default.
- W4310331856 modified "2023-09-26" @default.
- W4310331856 title "Regioselective α-addition of vinylogous α-ketoester enolate in organocatalytic asymmetric Michael reactions: enantioselective synthesis of Rauhut–Currier type products" @default.
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- W4310331856 doi "https://doi.org/10.1039/d2ra06416b" @default.
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