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- W4310335129 abstract "We report a tri-n-butyl phosphine catalyzed regio- and stereo-selective hydroboration of ynamides to yield (Z)-β-borylenamides in good yields. Surprisingly, a formal cis addition to the triple bond was observed as confirmed by NMR and X-ray crystallography. 31P NMR studies suggest that a zwitterionic vinylphosphonium intermediate is key in the mechanism. The resulting products were further transformed to β-CF3 enamides via stereoretentive trifluoromethylation." @default.
- W4310335129 created "2022-12-08" @default.
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- W4310335129 date "2022-01-01" @default.
- W4310335129 modified "2023-10-14" @default.
- W4310335129 title "Phosphine-catalyzed regio- and stereo-selective hydroboration of ynamides to (<i>Z</i>)-β-borylenamides" @default.
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- W4310335129 doi "https://doi.org/10.1039/d2cc04543e" @default.
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