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- W4310351753 abstract "Abstract The transition metal-catalysed Guerbet reaction allows the utilisation of feedstock alcohols and provides a direct and benign approach for the construction of C–C bonds. Herein, we describe the first non-noble metal manganese catalytic system that enables the efficient synthesis of higher-order alcohols via the cross-coupling of biomass-derived ethanol with primary alcohols. The process proceeded with high selectivity in the presence of a well-defined manganese pincer complex under solvent-free conditions. Catalyst loadings as low as 0.03 mol% can be used, leading to a record turnover number of 2336. A wide range of benzylic alcohols (> 20 examples) and aliphatic alcohols can be converted to longer linear alcohols in high yields and with excellent functional group tolerance." @default.
- W4310351753 created "2022-12-09" @default.
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- W4310351753 date "2022-11-29" @default.
- W4310351753 modified "2023-10-15" @default.
- W4310351753 title "Manganese-catalysed Selective Upgrading of Primary Alcohols with Ethanol under Solvent-free Conditions" @default.
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- W4310351753 doi "https://doi.org/10.21203/rs.3.rs-2294017/v1" @default.
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