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- W4310367761 abstract "Abstract Dynamic kinetic resolutions of racemic compounds provide elegant synthetic possibilities for the preparation of valuable enantiopure organic molecules with a theoretical maximum 100% yield. This chapter describes the combination of stereoselective enzymatic methods with suitable conditions for the racemization of the slow-reacting enantiomer from racemates of various types of compounds, such as alcohols, amines, and amino acids, for the synthesis of biologically active compounds and natural products. This contribution has been divided into three main topics based on the enzyme that catalyzes the asymmetric transformation and the racemization conditions of choice. These are: (i) the use of hydrolases and metal species; (ii) the use of hydrolases without requiring a metal catalyst for the racemization step; (iii) the use of other enzyme classes. A selection of scalable experimental procedures is provided in each case to demonstrate the robustness of the methodology described." @default.
- W4310367761 created "2022-12-09" @default.
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- W4310367761 date "2023-01-01" @default.
- W4310367761 modified "2023-09-24" @default.
- W4310367761 title "7 Applications of Chemoenzymatic Dynamic Kinetic Resolution for the Synthesis of Biologically Active Compounds and Natural Products" @default.
- W4310367761 doi "https://doi.org/10.1055/sos-sd-237-00092" @default.
- W4310367761 hasPublicationYear "2023" @default.
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