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- W4310462414 abstract "Herein we reported the use of Earth-abundant iron as the catalytic metal in the presence of Mn to induce difluorobromoacetates to form carbon radicals, which reacted with trifluoromethyl olefins followed by β-F elimination to generate the corresponding gem-difluoroolefins. The cross-electrophile coupling displayed excellent functional group tolerance and broad substrate scope under mild reductive conditions, affording a large number of polyfluorinated compounds, which could be further transformed to other valuable molecules." @default.
- W4310462414 created "2022-12-10" @default.
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- W4310462414 date "2022-01-01" @default.
- W4310462414 modified "2023-10-03" @default.
- W4310462414 title "Iron-catalysed reductive coupling for the synthesis of polyfluorinated compounds" @default.
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- W4310462414 doi "https://doi.org/10.1039/d2cc06022a" @default.
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