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- W4310463044 abstract "Racemic and enantiopure ferrocene-based P-chiral amidophosphinates have been simply and stereoselectively synthesized by ortho-lithiation of rac- or (R)-Ugi's amine and further reaction with amidochlorophenylphosphinate Cl-P(O)(Ph)NEt2. This is the first example of an asymmetric reaction of ortho-lithiated Ugi's amine with tetracoordinated phosphorus(V) chlorides. The structures of rac- and (R)-Ugi's amine ferrocenyl(phenyl)phosphinic acid N,N-diethylamide have been extensively studied experimentally (NMR, X-ray analysis, electrochemistry). The CV first peak refers to the oxidation of the amine fragment, which is clearly seen when (R)-Ugi's amine ferrocenyl(phenyl)phosphinic acid N,N-diethylamide reacts with anhydrous acid. The addition of two equivalents of CF3COOH leads to the protonation of nitrogen atoms, and a classical reversible wave of oxidation of Fe(II) to Fe(III) is observed." @default.
- W4310463044 created "2022-12-10" @default.
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- W4310463044 date "2022-01-01" @default.
- W4310463044 modified "2023-10-17" @default.
- W4310463044 title "Ferrocene-based <i>P</i>-chiral amidophosphinate: stereoselective synthesis and X-ray structural study" @default.
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- W4310463044 doi "https://doi.org/10.1039/d2dt02930h" @default.
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