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• W4310568786 abstract "A straightforward three-component transformation for the preparation of functionalized benzosultams under TM-free and mild reaction conditions was described, in which easy-to-handle Na2S2O5, available bromodifluoroalkyl reagent, and N-(2-haloaryl) cyanamide were employed. Na2S2O5 was essential to the generation of difluoroalkyl radical, SO2 fixation, and cyclization, which enabled efficient construction of target products in a sustainable manner. A broad substrate scope and modular feature made this protocol attractive for exploring the chemical space of the construction of cyclic sulfonamides." @default.
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• W4310568786 date "2022-12-01" @default.
• W4310568786 modified "2023-10-18" @default.
• W4310568786 title "Multicomponent Cyclization with an Inorganic Sulfur Dioxide Surrogate: Straightforward Construction of Difluorinated Benzosultams" @default.
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• W4310568786 doi "https://doi.org/10.1021/acs.orglett.2c03771" @default.
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