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- W4310596393 endingPage "451" @default.
- W4310596393 startingPage "412" @default.
- W4310596393 abstract "Covering: 2009 to 2021Biosynthetically, most of the syntheses of triterpenes follow the cascade cyclization and rearrangement of the acyclic precursors viz., squalene (S) and 2,3-oxidosqualene (OS), which lead to the very well known tetra- and pentacyclic triterpene skeletons. Aside from these, numerous other triterpenoid molecules are also reported from various natural sources and their structures are derived from S and OS via some unusual cyclization operations which are different from the usual tetra- and pentacyclic frameworks. Numerous compelling advances have been made and reported in the identification of these unusual cyclized mono-, di-, tri- and tetracyclic triterpenes between 2009 and 2021. Besides a dramatic increase in the newly isolated uncommon cyclized triterpenoids, substantial progress in the (bio)-synthesis of these triterpenes has been published along with significant progress in their biological effects. In this review, 180 new unusual cyclized triterpenoids together with their demonstrated biogenetic pathways, syntheses and biological effects will be categorized and discussed." @default.
- W4310596393 created "2022-12-12" @default.
- W4310596393 creator A5001118350 @default.
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- W4310596393 creator A5026804109 @default.
- W4310596393 creator A5030777903 @default.
- W4310596393 creator A5083054946 @default.
- W4310596393 date "2023-01-01" @default.
- W4310596393 modified "2023-10-17" @default.
- W4310596393 title "Unusually cyclized triterpenoids: occurrence, biosynthesis and chemical synthesis" @default.
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