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• W4310602960 endingPage "16457" @default.
• W4310602960 startingPage "16449" @default.
• W4310602960 abstract "The replacement of fossil resources with biomass resources in the construction of N-heterocycles is rapidly attracting research interest. Herein, we report palladium-catalyzed selective hydrogenative coupling of nitroarenes and phenols based on a transfer hydrogenation strategy, allowing straightforward access to spirocyclic pyrrolo- and indolo-fused quinoxalines, a class of compounds found in numerous natural alkaloids. The synthetic protocol is characterized by a broad substrate scope and the utilization of biomass-derived reactants and commercially available catalysts. In such transformations, high-pressure and explosive hydrogen are not required. This report provides a new protocol for converting biomass-derived phenols into value-added nitrogen-containing chemicals." @default.
• W4310602960 created "2022-12-12" @default.
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• W4310602960 date "2022-12-01" @default.
• W4310602960 modified "2023-10-16" @default.
• W4310602960 title "Construction of Spirocyclic Pyrrolo[1,2-<i>a</i>]quinoxalines via Palladium-Catalyzed Hydrogenative Coupling of Phenols and Nitroarenes" @default.
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• W4310602960 doi "https://doi.org/10.1021/acs.joc.2c02158" @default.
• W4310602960 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36455265" @default.
• W4310602960 hasPublicationYear "2022" @default.
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