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• W4310659831 startingPage "174" @default.
• W4310659831 abstract "Polyimides (PIs) with super heat-resistance and ultralow coefficient of thermal expansion (CTE) are required urgently to employ as plastic substrates in flexible-display devices. To attain the target properties, we designed and synthesized a novel bibenzimidazole diamine characterized in having a N-phenyl group, namely 1-phenyl-2,2′-bibenzoimidazole-5,5′-diamine (PhDABZ), and focused on an aromatic poly(benzimidazole imide) series derived from 1,2,4,5-benzenetetracarboxylic (PMDA). Incorporating bibenzimidazole and N-substituent effectively increase the interchain interaction and chance for flexible film formation, which provides the PIs with high glass-transition temperature (Tg > 480 °C) and dimensional stability (CTE < 10 ppm K−1). These data provide a feasible method to achieve higher thermal properties of PIs." @default.
• W4310659831 created "2022-12-14" @default.
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• W4310659831 date "2022-12-04" @default.
• W4310659831 modified "2023-09-29" @default.
• W4310659831 title "Polyimides with super‐high <i>T</i> _g and ultra‐low coefficient of thermal expansion from <i>N</i> ‐substituted bibenzimidazole diamines" @default.
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• W4310659831 doi "https://doi.org/10.1002/pol.20220623" @default.
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