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- W4310704557 abstract "Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the built-in-base ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (Tg ) via differential scanning calorimetry (DSC)." @default.
- W4310704557 created "2022-12-16" @default.
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- W4310704557 date "2022-12-28" @default.
- W4310704557 modified "2023-10-10" @default.
- W4310704557 title "Efficient Synthesis of Novel Plasticizers by Direct Palladium‐Catalyzed Di‐ or Multi‐carbonylations" @default.
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- W4310704557 doi "https://doi.org/10.1002/anie.202214706" @default.
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