Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310705353> ?p ?o ?g. }
- W4310705353 abstract "The transition metal-catalyzed cross-coupling reaction with Fischer metal carbene intermediates bearing an electron-rich alkoxyl or siloxyl group remains a big challenge due to the lack of readily available corresponding carbene precursors. Herein, we report the coupling of alkynes with the Fischer-type copper carbene species bearing a α-siloxyl group, which could be in situ generated from acylsilanes catalytically under photoirradiation and redox-neutral conditions. The side-arm modified bisoxazoline (SaBox) ligands prove to be crucial for this coupling reaction, which provides the corresponding alkynyl alcohol in high yields with remarkable heterocycle tolerance and broad substrate scope." @default.
- W4310705353 created "2022-12-16" @default.
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- W4310705353 creator A5069099445 @default.
- W4310705353 date "2022-12-22" @default.
- W4310705353 modified "2023-10-06" @default.
- W4310705353 title "Cu/ <i>Sa</i> Box‐Catalyzed Photoinduced Coupling of Acylsilanes with Alkynes" @default.
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- W4310705353 doi "https://doi.org/10.1002/anie.202216373" @default.
- W4310705353 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36465061" @default.
- W4310705353 hasPublicationYear "2022" @default.
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