Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310706088> ?p ?o ?g. }
- W4310706088 abstract "The methanol solvomorph 1 ⋅ 2MeOH of the cobalt(II) complex [Co(LSal,2-Ph )2 ] (1) with the sterically demanding Schiff-base ligand 2-(([1,1'-biphenyl]-2-ylimino)methyl)phenol (HLSal,2-Ph ) shows the thus far largest dihedral twist distortion between the two chelate planes compared to an ideal pseudotetrahedral arrangement. The cobalt(II) ion in 1 ⋅ 2MeOH exhibits an easy-axis anisotropy leading to a spin-reversal barrier of 55.3 cm-1 , which corresponds to an increase of about 17 % induced by the larger dihedral twist compared to the solvent-free complex 1. The magnetic relaxation for 1 ⋅ 2MeOH is significantly slower compared to 1. An in-depth frequency-domain Fourier-transform (FD-FT) THz-EPR study not only allowed the direct measurement of the magnetic transition between the two lowest Kramers doublets for the cobalt(II) complexes, but also revealed the presence of spin-phonon coupling. Interestingly, a similar dihedral twist correlation is also observed for a second pair of cobalt(II)-based solvomorphs, which could be benchmarked by FD-FT THz-EPR." @default.
- W4310706088 created "2022-12-16" @default.
- W4310706088 creator A5004286635 @default.
- W4310706088 creator A5027628260 @default.
- W4310706088 creator A5040212286 @default.
- W4310706088 creator A5042644187 @default.
- W4310706088 creator A5044435445 @default.
- W4310706088 creator A5058572368 @default.
- W4310706088 creator A5077991577 @default.
- W4310706088 creator A5085641769 @default.
- W4310706088 date "2023-02-03" @default.
- W4310706088 modified "2023-10-15" @default.
- W4310706088 title "Magnetic Anisotropy and Relaxation of Pseudotetrahedral [N <sub>2</sub> O <sub>2</sub> ] Bis‐Chelate Cobalt(II) Single‐Ion Magnets Controlled by Dihedral Twist Through Solvomorphism" @default.
- W4310706088 cites W1969360633 @default.
- W4310706088 cites W1973537412 @default.
- W4310706088 cites W1975434096 @default.
- W4310706088 cites W1979303409 @default.
- W4310706088 cites W1985172803 @default.
- W4310706088 cites W1988091937 @default.
- W4310706088 cites W2024175762 @default.
- W4310706088 cites W2033648942 @default.
- W4310706088 cites W2036888076 @default.
- W4310706088 cites W2044150055 @default.
- W4310706088 cites W2079604487 @default.
- W4310706088 cites W2088712172 @default.
- W4310706088 cites W2097764239 @default.
- W4310706088 cites W2100113961 @default.
- W4310706088 cites W2101547779 @default.
- W4310706088 cites W2117867509 @default.
- W4310706088 cites W2132454074 @default.
- W4310706088 cites W2146051607 @default.
- W4310706088 cites W2146695448 @default.
- W4310706088 cites W2154229956 @default.
- W4310706088 cites W2211195160 @default.
- W4310706088 cites W2278356249 @default.
- W4310706088 cites W2316457736 @default.
- W4310706088 cites W2317109302 @default.
- W4310706088 cites W2330164190 @default.
- W4310706088 cites W2342446537 @default.
- W4310706088 cites W2400867991 @default.
- W4310706088 cites W2466015345 @default.
- W4310706088 cites W2521587834 @default.
- W4310706088 cites W2591086733 @default.
- W4310706088 cites W2620991516 @default.
- W4310706088 cites W2808513408 @default.
- W4310706088 cites W2971968767 @default.
- W4310706088 cites W2984661711 @default.
- W4310706088 cites W3008371344 @default.
- W4310706088 cites W3016367067 @default.
- W4310706088 cites W3036562412 @default.
- W4310706088 cites W3045612742 @default.
- W4310706088 cites W3107560417 @default.
- W4310706088 cites W3119025388 @default.
- W4310706088 cites W3158216970 @default.
- W4310706088 cites W3203069572 @default.
- W4310706088 cites W4232406903 @default.
- W4310706088 cites W4290202296 @default.
- W4310706088 cites W4307025833 @default.
- W4310706088 doi "https://doi.org/10.1002/chem.202202966" @default.
- W4310706088 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36468847" @default.
- W4310706088 hasPublicationYear "2023" @default.
- W4310706088 type Work @default.
- W4310706088 citedByCount "1" @default.
- W4310706088 countsByYear W43107060882023 @default.
- W4310706088 crossrefType "journal-article" @default.
- W4310706088 hasAuthorship W4310706088A5004286635 @default.
- W4310706088 hasAuthorship W4310706088A5027628260 @default.
- W4310706088 hasAuthorship W4310706088A5040212286 @default.
- W4310706088 hasAuthorship W4310706088A5042644187 @default.
- W4310706088 hasAuthorship W4310706088A5044435445 @default.
- W4310706088 hasAuthorship W4310706088A5058572368 @default.
- W4310706088 hasAuthorship W4310706088A5077991577 @default.
- W4310706088 hasAuthorship W4310706088A5085641769 @default.
- W4310706088 hasBestOaLocation W43107060881 @default.
- W4310706088 hasConcept C112887158 @default.
- W4310706088 hasConcept C113196181 @default.
- W4310706088 hasConcept C115260700 @default.
- W4310706088 hasConcept C121332964 @default.
- W4310706088 hasConcept C124712363 @default.
- W4310706088 hasConcept C145148216 @default.
- W4310706088 hasConcept C178790620 @default.
- W4310706088 hasConcept C179104552 @default.
- W4310706088 hasConcept C185592680 @default.
- W4310706088 hasConcept C187961010 @default.
- W4310706088 hasConcept C201194858 @default.
- W4310706088 hasConcept C26873012 @default.
- W4310706088 hasConcept C32546565 @default.
- W4310706088 hasConcept C32909587 @default.
- W4310706088 hasConcept C32938098 @default.
- W4310706088 hasConcept C43617362 @default.
- W4310706088 hasConcept C46141821 @default.
- W4310706088 hasConcept C515602321 @default.
- W4310706088 hasConcept C62520636 @default.
- W4310706088 hasConcept C71240020 @default.
- W4310706088 hasConcept C8010536 @default.
- W4310706088 hasConcept C89025888 @default.
- W4310706088 hasConceptScore W4310706088C112887158 @default.
- W4310706088 hasConceptScore W4310706088C113196181 @default.
- W4310706088 hasConceptScore W4310706088C115260700 @default.
- W4310706088 hasConceptScore W4310706088C121332964 @default.