Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310947368> ?p ?o ?g. }
- W4310947368 abstract "Vacancy engineering is deemed as one of the powerful protocols to tune the catalytic activity of electrocatalysts. Herein, Se-vacancy with charge polarization is created in the NiSe2 structure (NiSe2 -VSe ) via a sequential phase conversion strategy. By a combined analysis of the Rietveld method, transient photovoltage spectra (TPV), in situ Raman and density functional theory (DFT) calculation, it is unequivocally discovered that the presence of charge-polarized Se-vacancy is beneficial for stabilizing the structure, decreasing the electron transfer kinetics, as well as optimizing the free adsorption energy of reaction intermediate during two-electron oxygen reduction reaction (2e- ORR). Benefiting from these merits, the as-prepared NiSe2 -VSe delivered the highest selectivity of 96% toward H2 O2 in alkaline media, together with a selectivity higher than 90% over the wide potential range from 0.25 to 0.55 V, ranking it in the top level among the previously reported transition metal-based electrocatalysts. Most notably, it also displayed admirable stability with only a slight selectivity decay after 5000 cycles of accelerated degradation test (ADT)." @default.
- W4310947368 created "2022-12-21" @default.
- W4310947368 creator A5009720807 @default.
- W4310947368 creator A5021345742 @default.
- W4310947368 creator A5021477500 @default.
- W4310947368 creator A5023363049 @default.
- W4310947368 creator A5029864603 @default.
- W4310947368 creator A5041526601 @default.
- W4310947368 creator A5076699693 @default.
- W4310947368 creator A5080470862 @default.
- W4310947368 creator A5082297994 @default.
- W4310947368 date "2022-12-07" @default.
- W4310947368 modified "2023-10-16" @default.
- W4310947368 title "Charge‐Polarized Selenium Vacancy in Nickel Diselenide Enabling Efficient and Stable Electrocatalytic Conversion of Oxygen to Hydrogen Peroxide" @default.
- W4310947368 cites W1964151256 @default.
- W4310947368 cites W1977225125 @default.
- W4310947368 cites W1983820397 @default.
- W4310947368 cites W1986447060 @default.
- W4310947368 cites W2061367556 @default.
- W4310947368 cites W2080475618 @default.
- W4310947368 cites W2085837328 @default.
- W4310947368 cites W2089819814 @default.
- W4310947368 cites W2154358568 @default.
- W4310947368 cites W2328832782 @default.
- W4310947368 cites W2771377027 @default.
- W4310947368 cites W2782723324 @default.
- W4310947368 cites W2785768358 @default.
- W4310947368 cites W2805559882 @default.
- W4310947368 cites W2886249127 @default.
- W4310947368 cites W2901462587 @default.
- W4310947368 cites W2907839920 @default.
- W4310947368 cites W2912861525 @default.
- W4310947368 cites W2914316573 @default.
- W4310947368 cites W2947738211 @default.
- W4310947368 cites W2959489985 @default.
- W4310947368 cites W2974426157 @default.
- W4310947368 cites W2986414975 @default.
- W4310947368 cites W2999727704 @default.
- W4310947368 cites W3009618524 @default.
- W4310947368 cites W3012441403 @default.
- W4310947368 cites W3017454980 @default.
- W4310947368 cites W3020883793 @default.
- W4310947368 cites W3026155039 @default.
- W4310947368 cites W3032105847 @default.
- W4310947368 cites W3034591340 @default.
- W4310947368 cites W3036377937 @default.
- W4310947368 cites W3042156029 @default.
- W4310947368 cites W3047586960 @default.
- W4310947368 cites W3048844153 @default.
- W4310947368 cites W3049581126 @default.
- W4310947368 cites W3049717288 @default.
- W4310947368 cites W3083836886 @default.
- W4310947368 cites W3101575078 @default.
- W4310947368 cites W3120567289 @default.
- W4310947368 cites W3134617340 @default.
- W4310947368 cites W3135710700 @default.
- W4310947368 cites W3173013707 @default.
- W4310947368 cites W3173018210 @default.
- W4310947368 cites W3175982281 @default.
- W4310947368 cites W3178877678 @default.
- W4310947368 cites W3198656291 @default.
- W4310947368 cites W3200117203 @default.
- W4310947368 cites W3206157328 @default.
- W4310947368 cites W3209833474 @default.
- W4310947368 cites W3213933740 @default.
- W4310947368 cites W4200318999 @default.
- W4310947368 cites W4200614601 @default.
- W4310947368 cites W4205181961 @default.
- W4310947368 cites W4210390682 @default.
- W4310947368 cites W4210398161 @default.
- W4310947368 cites W4212916984 @default.
- W4310947368 cites W4214809269 @default.
- W4310947368 cites W4220806205 @default.
- W4310947368 cites W4280509676 @default.
- W4310947368 cites W4283361388 @default.
- W4310947368 cites W4310947368 @default.
- W4310947368 doi "https://doi.org/10.1002/advs.202205347" @default.
- W4310947368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36479607" @default.
- W4310947368 hasPublicationYear "2022" @default.
- W4310947368 type Work @default.
- W4310947368 citedByCount "6" @default.
- W4310947368 countsByYear W43109473682022 @default.
- W4310947368 countsByYear W43109473682023 @default.
- W4310947368 crossrefType "journal-article" @default.
- W4310947368 hasAuthorship W4310947368A5009720807 @default.
- W4310947368 hasAuthorship W4310947368A5021345742 @default.
- W4310947368 hasAuthorship W4310947368A5021477500 @default.
- W4310947368 hasAuthorship W4310947368A5023363049 @default.
- W4310947368 hasAuthorship W4310947368A5029864603 @default.
- W4310947368 hasAuthorship W4310947368A5041526601 @default.
- W4310947368 hasAuthorship W4310947368A5076699693 @default.
- W4310947368 hasAuthorship W4310947368A5080470862 @default.
- W4310947368 hasAuthorship W4310947368A5082297994 @default.
- W4310947368 hasBestOaLocation W43109473682 @default.
- W4310947368 hasConcept C114221277 @default.
- W4310947368 hasConcept C118792377 @default.
- W4310947368 hasConcept C120665830 @default.
- W4310947368 hasConcept C121332964 @default.
- W4310947368 hasConcept C161790260 @default.
- W4310947368 hasConcept C178790620 @default.