Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310955256> ?p ?o ?g. }
- W4310955256 endingPage "9439" @default.
- W4310955256 startingPage "9423" @default.
- W4310955256 abstract "Many distinct vibrational states contribute to the congested photoelectron spectra of hot polyatomic anions. This often makes the complete Franck–Condon (FC) analysis both impractical and unnecessary. Although it is common to limit the FC calculations to a subset of the FC-active modes, such a limited approach is strictly applicable to the ground-state (cold) anions only. At high temperatures, all vibrational modes participate in thermal excitation, and the FC and thermal activities become intertwined. We report the photoelectron spectra of ∼700 K phenide (C6H5–) obtained at 355 nm (3.49 eV), 532 nm (2.33 eV), and 611 nm (2.03 eV) and describe several practical models that help interpret and analyze the results. Among them are the active-modes model, the active modes + dark bath and the active modes + bright bath models, and, finally, the energy-conservation model. The models combine the results of limited (and, therefore, feasible) FC calculations with statistical analysis and provide efficient means of determining the ion temperature from the broad and congested photoelectron spectra. The described capability can be applied to hot plasmas, the collisional excitation or cooling of ions, and evaporative cooling in cluster ions." @default.
- W4310955256 created "2022-12-21" @default.
- W4310955256 creator A5021940253 @default.
- W4310955256 creator A5069881558 @default.
- W4310955256 date "2022-12-09" @default.
- W4310955256 modified "2023-10-17" @default.
- W4310955256 title "Photoelectron Spectra of Hot Polyatomic Ions: A Statistical Treatment of Phenide" @default.
- W4310955256 cites W1635585509 @default.
- W4310955256 cites W1964818722 @default.
- W4310955256 cites W1970372853 @default.
- W4310955256 cites W1974633466 @default.
- W4310955256 cites W1978935702 @default.
- W4310955256 cites W1982845586 @default.
- W4310955256 cites W1984098954 @default.
- W4310955256 cites W1984570113 @default.
- W4310955256 cites W1988890926 @default.
- W4310955256 cites W1999447325 @default.
- W4310955256 cites W2001303401 @default.
- W4310955256 cites W2001374126 @default.
- W4310955256 cites W2005823075 @default.
- W4310955256 cites W2011796905 @default.
- W4310955256 cites W2014599177 @default.
- W4310955256 cites W2020083221 @default.
- W4310955256 cites W2022338872 @default.
- W4310955256 cites W2024016948 @default.
- W4310955256 cites W2025277627 @default.
- W4310955256 cites W2025288309 @default.
- W4310955256 cites W2026172453 @default.
- W4310955256 cites W2029510908 @default.
- W4310955256 cites W2033051992 @default.
- W4310955256 cites W2039816741 @default.
- W4310955256 cites W2049300473 @default.
- W4310955256 cites W2050485262 @default.
- W4310955256 cites W2065079246 @default.
- W4310955256 cites W2066527616 @default.
- W4310955256 cites W2066529877 @default.
- W4310955256 cites W2068241704 @default.
- W4310955256 cites W2068259753 @default.
- W4310955256 cites W2070754970 @default.
- W4310955256 cites W2081636852 @default.
- W4310955256 cites W2097690696 @default.
- W4310955256 cites W2100949693 @default.
- W4310955256 cites W2135494969 @default.
- W4310955256 cites W2166603911 @default.
- W4310955256 cites W2177270354 @default.
- W4310955256 cites W2316983361 @default.
- W4310955256 cites W2326694910 @default.
- W4310955256 cites W2332931085 @default.
- W4310955256 cites W2582717733 @default.
- W4310955256 cites W2582943404 @default.
- W4310955256 cites W2890019920 @default.
- W4310955256 cites W2973290003 @default.
- W4310955256 cites W3022900486 @default.
- W4310955256 cites W3098317889 @default.
- W4310955256 cites W3144163481 @default.
- W4310955256 cites W3150700559 @default.
- W4310955256 cites W3166593966 @default.
- W4310955256 cites W3211016181 @default.
- W4310955256 cites W4280530947 @default.
- W4310955256 cites W4285730296 @default.
- W4310955256 doi "https://doi.org/10.1021/acs.jpca.2c07361" @default.
- W4310955256 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36484501" @default.
- W4310955256 hasPublicationYear "2022" @default.
- W4310955256 type Work @default.
- W4310955256 citedByCount "3" @default.
- W4310955256 countsByYear W43109552562023 @default.
- W4310955256 crossrefType "journal-article" @default.
- W4310955256 hasAuthorship W4310955256A5021940253 @default.
- W4310955256 hasAuthorship W4310955256A5069881558 @default.
- W4310955256 hasConcept C121332964 @default.
- W4310955256 hasConcept C1276947 @default.
- W4310955256 hasConcept C145148216 @default.
- W4310955256 hasConcept C164866538 @default.
- W4310955256 hasConcept C175708663 @default.
- W4310955256 hasConcept C178790620 @default.
- W4310955256 hasConcept C184779094 @default.
- W4310955256 hasConcept C185592680 @default.
- W4310955256 hasConcept C199360897 @default.
- W4310955256 hasConcept C204530211 @default.
- W4310955256 hasConcept C41008148 @default.
- W4310955256 hasConcept C46141821 @default.
- W4310955256 hasConcept C4839761 @default.
- W4310955256 hasConcept C62520636 @default.
- W4310955256 hasConcept C66594872 @default.
- W4310955256 hasConcept C83581075 @default.
- W4310955256 hasConcept C97355855 @default.
- W4310955256 hasConceptScore W4310955256C121332964 @default.
- W4310955256 hasConceptScore W4310955256C1276947 @default.
- W4310955256 hasConceptScore W4310955256C145148216 @default.
- W4310955256 hasConceptScore W4310955256C164866538 @default.
- W4310955256 hasConceptScore W4310955256C175708663 @default.
- W4310955256 hasConceptScore W4310955256C178790620 @default.
- W4310955256 hasConceptScore W4310955256C184779094 @default.
- W4310955256 hasConceptScore W4310955256C185592680 @default.
- W4310955256 hasConceptScore W4310955256C199360897 @default.
- W4310955256 hasConceptScore W4310955256C204530211 @default.
- W4310955256 hasConceptScore W4310955256C41008148 @default.
- W4310955256 hasConceptScore W4310955256C46141821 @default.