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• W4310962214 abstract "Disulfide bonds of 2-isocyanatophenyl methyl disulfide and 2-endo-isocyanato-6-endo-(methyldisulfanyl)bicyclo[2.2.1]heptane showed neighboring group participation in the formation of thiocarbamates. Natural Bond Orbital (NBO) analyses revealed that the unusual nucleophilicity requires a rigid through-space interaction between a lone pair of the disulfide bond and an antibonding orbital of isocyanate." @default.
• W4310962214 created "2022-12-21" @default.
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• W4310962214 date "2023-01-01" @default.
• W4310962214 modified "2023-09-29" @default.
• W4310962214 title "Synthetic and computational investigation of neighboring group participation by a nucleophilic disulfide bond" @default.
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• W4310962214 doi "https://doi.org/10.1039/d2ob01574a" @default.
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