Matches in SemOpenAlex for { <https://semopenalex.org/work/W4310963930> ?p ?o ?g. }
- W4310963930 abstract "Herein, the synthesis and X-ray structures of three α,β two wall aryl-extended calix[4]pyrroles having either identical (symmetrically substituted) or different (non-symmetrically substituted) meso-aryl substituents (aryl=4-ethynylphenyl and 4-iodophenyl) are reported. The X-ray structure of the co-crystal formed by the two symmetrically substituted calix[4]pyrroles is also described. In the solid state, all studied α,β-calix[4]pyrroles exhibit a 1,3-alternate conformation with two co-crystallized acetonitrile solvent molecules H-bonded to adjacent cis-pyrrole rings. Remarkably, the 1,3-conformer of the non-symmetrically substituted iodophenyl/ethynylphenyl compound is intrinsically chiral. The two enantiomers are present in the average asymmetric unit in a 65 : 35 occupancy ratio displaying a head-to-tail directional disorder. This is due to the functional complementarity and the isosteric and isoelectronic properties of the para-substituents: iodo and ethynyl. That is, the negative belt of iodine is similar to the negative π-system of the C≡C triple bond and the σ-hole in the iodine atom is similar to the positive proton at the C≡C-H group." @default.
- W4310963930 created "2022-12-21" @default.
- W4310963930 creator A5005597587 @default.
- W4310963930 creator A5007717229 @default.
- W4310963930 creator A5037112571 @default.
- W4310963930 creator A5091406291 @default.
- W4310963930 date "2022-12-23" @default.
- W4310963930 modified "2023-10-12" @default.
- W4310963930 title "Interchangeability and Disorder in the Solid‐State Structures of “Two Wall” Calix[4]pyrroles Equipped with Iodine and Ethynyl <i>para</i>‐Substituents" @default.
- W4310963930 cites W1966750682 @default.
- W4310963930 cites W1969360633 @default.
- W4310963930 cites W1970629894 @default.
- W4310963930 cites W2008423326 @default.
- W4310963930 cites W2028022118 @default.
- W4310963930 cites W2029667189 @default.
- W4310963930 cites W2044591029 @default.
- W4310963930 cites W2051469879 @default.
- W4310963930 cites W2059885388 @default.
- W4310963930 cites W2092157292 @default.
- W4310963930 cites W2097925885 @default.
- W4310963930 cites W2103463892 @default.
- W4310963930 cites W2119547517 @default.
- W4310963930 cites W2132454074 @default.
- W4310963930 cites W2132525235 @default.
- W4310963930 cites W2144332006 @default.
- W4310963930 cites W2146426024 @default.
- W4310963930 cites W2150697053 @default.
- W4310963930 cites W2161038614 @default.
- W4310963930 cites W2171422241 @default.
- W4310963930 cites W2265596863 @default.
- W4310963930 cites W2333809830 @default.
- W4310963930 cites W2333856213 @default.
- W4310963930 cites W2476296605 @default.
- W4310963930 cites W2792863608 @default.
- W4310963930 cites W3010020228 @default.
- W4310963930 cites W3153251993 @default.
- W4310963930 cites W3162780401 @default.
- W4310963930 cites W3178048268 @default.
- W4310963930 cites W3200851644 @default.
- W4310963930 cites W3203399030 @default.
- W4310963930 cites W3204501668 @default.
- W4310963930 cites W3214419550 @default.
- W4310963930 cites W4206167113 @default.
- W4310963930 cites W4231906938 @default.
- W4310963930 cites W4233329780 @default.
- W4310963930 cites W4248971002 @default.
- W4310963930 cites W4253643476 @default.
- W4310963930 cites W4253978574 @default.
- W4310963930 cites W4285240219 @default.
- W4310963930 doi "https://doi.org/10.1002/asia.202201192" @default.
- W4310963930 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36485017" @default.
- W4310963930 hasPublicationYear "2022" @default.
- W4310963930 type Work @default.
- W4310963930 citedByCount "0" @default.
- W4310963930 crossrefType "journal-article" @default.
- W4310963930 hasAuthorship W4310963930A5005597587 @default.
- W4310963930 hasAuthorship W4310963930A5007717229 @default.
- W4310963930 hasAuthorship W4310963930A5037112571 @default.
- W4310963930 hasAuthorship W4310963930A5091406291 @default.
- W4310963930 hasConcept C107814960 @default.
- W4310963930 hasConcept C115624301 @default.
- W4310963930 hasConcept C147789679 @default.
- W4310963930 hasConcept C178790620 @default.
- W4310963930 hasConcept C185592680 @default.
- W4310963930 hasConcept C18705241 @default.
- W4310963930 hasConcept C2777463227 @default.
- W4310963930 hasConcept C2779400197 @default.
- W4310963930 hasConcept C2780263894 @default.
- W4310963930 hasConcept C2781076698 @default.
- W4310963930 hasConcept C32909587 @default.
- W4310963930 hasConcept C486523 @default.
- W4310963930 hasConcept C539932907 @default.
- W4310963930 hasConcept C71240020 @default.
- W4310963930 hasConcept C8010536 @default.
- W4310963930 hasConceptScore W4310963930C107814960 @default.
- W4310963930 hasConceptScore W4310963930C115624301 @default.
- W4310963930 hasConceptScore W4310963930C147789679 @default.
- W4310963930 hasConceptScore W4310963930C178790620 @default.
- W4310963930 hasConceptScore W4310963930C185592680 @default.
- W4310963930 hasConceptScore W4310963930C18705241 @default.
- W4310963930 hasConceptScore W4310963930C2777463227 @default.
- W4310963930 hasConceptScore W4310963930C2779400197 @default.
- W4310963930 hasConceptScore W4310963930C2780263894 @default.
- W4310963930 hasConceptScore W4310963930C2781076698 @default.
- W4310963930 hasConceptScore W4310963930C32909587 @default.
- W4310963930 hasConceptScore W4310963930C486523 @default.
- W4310963930 hasConceptScore W4310963930C539932907 @default.
- W4310963930 hasConceptScore W4310963930C71240020 @default.
- W4310963930 hasConceptScore W4310963930C8010536 @default.
- W4310963930 hasFunder F4320322930 @default.
- W4310963930 hasFunder F4320334830 @default.
- W4310963930 hasIssue "3" @default.
- W4310963930 hasLocation W43109639301 @default.
- W4310963930 hasLocation W43109639302 @default.
- W4310963930 hasOpenAccess W4310963930 @default.
- W4310963930 hasPrimaryLocation W43109639301 @default.
- W4310963930 hasRelatedWork W1972863456 @default.
- W4310963930 hasRelatedWork W1994100022 @default.
- W4310963930 hasRelatedWork W2023036309 @default.
- W4310963930 hasRelatedWork W2052399476 @default.