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- W4310984964 abstract "Abstract Herein, the development of phosphorus and boron doped graphitic carbon nitride/zeolite (P and B doped g-C 3 N 4 -zeolite) catalyst under three-step heating conditions was performed. The first step is to prepare g-C 3 N 4 synthesis from urea at 500 o C. In the second step, the production of B-doped zeolite-g-C 3 N 4 catalyst by calcination of g-C 3 N 4 and zeolite obtained at a ratio of 1:1 with boric acid at 500 o C. In the third step, the obtained B doped zeolite- g-C 3 N 4 catalyst consists of the preparation of B and P doped g-C 3 N 4 -zeolite catalyst as a result of hydrothermal method with phosphoric acid. Characterization studies of the obtained catalysts were carried out with XRD, SEM-EDX, FTIR and XPS analyzes. These obtained catalysts were used as a metal free catalyst in the production of hydrogen (H 2 -P) by sodium borohydride in methanol(NaBH 4 -MR) for the first time in the literature. Hydrogen production rate (HGR) value for B and P doped g-C 3 N 4 -zeolite catalysts was 6250 ml min − 1 g − 1 ." @default.
- W4310984964 created "2022-12-22" @default.
- W4310984964 creator A5087849835 @default.
- W4310984964 date "2022-11-29" @default.
- W4310984964 modified "2023-10-18" @default.
- W4310984964 title "Metal-free phosphorus and boron doped graphitic carbon nitride/zeolite hetero-linked particles for highly efficient green hydrogen production in methanol" @default.
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- W4310984964 doi "https://doi.org/10.21203/rs.3.rs-2246219/v1" @default.
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