Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311139619> ?p ?o ?g. }
- W4311139619 abstract "Li-ion batteries are considered prospective candidates for storage systems because of their high energy density and long cycling life. However, the use of organic electrolytes increases the risk of explosion and fire. Hence, all-solid-state Li-ion batteries have attracted considerable attention because the use of solid electrolytes avoids the combustion of electrolytes and explosions, and enhances the performance of batteries. Garnet-type oxides are commonly used solid electrolytes. The common Ta-doped Li7La3Zr2O12 can react easily with CO2 and H2O in air, and its ionic conductivity decays after contact with air. In this study, a novel garnet-type, high-entropy oxide, Li6.4La3Zr0.4Ta0.4Nb0.4Y0.6W0.2O12 (LLZTNYWO), is successfully synthesized as a solid electrolyte for Li-ion batteries,using a conventional solid-state method. Ta, Nb, Y, and W are used as substitutes for Zr, which significantly increase conductivity, have high stability in air, and a lower sintering temperature. LLZTNYWO achieves higher Li-ion conductivity at 1.16 × 10−4 S cm−1 compared to mono-doped Li6.6La3Zr1.6Ta0.4O12 (6.57 × 10−5 S cm−1), Li6.6La3Zr1.6Nb0.4O12 (2.19 × 10−5 S cm−1), and Li6.2La3Zr1.6W0.4O12 (1.16 × 10−4 S cm−1). Additionally, it exhibits higher ionic conductivity compared to equimolar Li5.8La3Zr0.4Ta0.4Nb0.4Y0.4W0.4O12 (1.95 × 10−5 S cm−1). The Li-ion conductivity of LLZTNYWO remains constant for 30 days in the atmosphere without decay, thereby revealing its excellent air stability. Furthermore, LLZTNYWO exhibits a remarkable electrochemical window of up to 6 V vs Li/Li+ and excellent electrochemical stability against Li metal after cycling at 0.1 mA·cm−2 for 2 h, which indicates that it is a promising solid electrolyte for Li-ion batteries." @default.
- W4311139619 created "2022-12-23" @default.
- W4311139619 creator A5009371832 @default.
- W4311139619 creator A5010783003 @default.
- W4311139619 creator A5019572026 @default.
- W4311139619 creator A5061542445 @default.
- W4311139619 creator A5061592993 @default.
- W4311139619 creator A5070537982 @default.
- W4311139619 creator A5084555578 @default.
- W4311139619 creator A5085579999 @default.
- W4311139619 creator A5088158028 @default.
- W4311139619 date "2022-12-01" @default.
- W4311139619 modified "2023-10-04" @default.
- W4311139619 title "A novel garnet-type high-entropy oxide as air-stable solid electrolyte for Li-ion batteries" @default.
- W4311139619 cites W1188141066 @default.
- W4311139619 cites W1532022075 @default.
- W4311139619 cites W1968729388 @default.
- W4311139619 cites W1985013794 @default.
- W4311139619 cites W1995831910 @default.
- W4311139619 cites W1998062017 @default.
- W4311139619 cites W2032952916 @default.
- W4311139619 cites W2039140542 @default.
- W4311139619 cites W2069691371 @default.
- W4311139619 cites W2097044885 @default.
- W4311139619 cites W2131059618 @default.
- W4311139619 cites W2152048732 @default.
- W4311139619 cites W2156562079 @default.
- W4311139619 cites W2167590372 @default.
- W4311139619 cites W2261135145 @default.
- W4311139619 cites W2313515426 @default.
- W4311139619 cites W2401730588 @default.
- W4311139619 cites W2605543661 @default.
- W4311139619 cites W2750682527 @default.
- W4311139619 cites W2766472028 @default.
- W4311139619 cites W2772004376 @default.
- W4311139619 cites W2789530326 @default.
- W4311139619 cites W2888579709 @default.
- W4311139619 cites W2898600870 @default.
- W4311139619 cites W2913909639 @default.
- W4311139619 cites W2940107393 @default.
- W4311139619 cites W2943731834 @default.
- W4311139619 cites W2974512415 @default.
- W4311139619 cites W2990529256 @default.
- W4311139619 cites W2996301349 @default.
- W4311139619 cites W3023997421 @default.
- W4311139619 cites W3107854976 @default.
- W4311139619 cites W3112567041 @default.
- W4311139619 cites W3129412890 @default.
- W4311139619 cites W3155282454 @default.
- W4311139619 cites W33652711 @default.
- W4311139619 cites W4206396037 @default.
- W4311139619 cites W4281770987 @default.
- W4311139619 doi "https://doi.org/10.1063/5.0123562" @default.
- W4311139619 hasPublicationYear "2022" @default.
- W4311139619 type Work @default.
- W4311139619 citedByCount "4" @default.
- W4311139619 countsByYear W43111396192023 @default.
- W4311139619 crossrefType "journal-article" @default.
- W4311139619 hasAuthorship W4311139619A5009371832 @default.
- W4311139619 hasAuthorship W4311139619A5010783003 @default.
- W4311139619 hasAuthorship W4311139619A5019572026 @default.
- W4311139619 hasAuthorship W4311139619A5061542445 @default.
- W4311139619 hasAuthorship W4311139619A5061592993 @default.
- W4311139619 hasAuthorship W4311139619A5070537982 @default.
- W4311139619 hasAuthorship W4311139619A5084555578 @default.
- W4311139619 hasAuthorship W4311139619A5085579999 @default.
- W4311139619 hasAuthorship W4311139619A5088158028 @default.
- W4311139619 hasBestOaLocation W43111396191 @default.
- W4311139619 hasConcept C109883240 @default.
- W4311139619 hasConcept C113196181 @default.
- W4311139619 hasConcept C127413603 @default.
- W4311139619 hasConcept C131540310 @default.
- W4311139619 hasConcept C138679309 @default.
- W4311139619 hasConcept C145148216 @default.
- W4311139619 hasConcept C147789679 @default.
- W4311139619 hasConcept C17525397 @default.
- W4311139619 hasConcept C178790620 @default.
- W4311139619 hasConcept C179104552 @default.
- W4311139619 hasConcept C185592680 @default.
- W4311139619 hasConcept C191897082 @default.
- W4311139619 hasConcept C192562407 @default.
- W4311139619 hasConcept C2777581544 @default.
- W4311139619 hasConcept C2779851234 @default.
- W4311139619 hasConcept C42360764 @default.
- W4311139619 hasConcept C68801617 @default.
- W4311139619 hasConceptScore W4311139619C109883240 @default.
- W4311139619 hasConceptScore W4311139619C113196181 @default.
- W4311139619 hasConceptScore W4311139619C127413603 @default.
- W4311139619 hasConceptScore W4311139619C131540310 @default.
- W4311139619 hasConceptScore W4311139619C138679309 @default.
- W4311139619 hasConceptScore W4311139619C145148216 @default.
- W4311139619 hasConceptScore W4311139619C147789679 @default.
- W4311139619 hasConceptScore W4311139619C17525397 @default.
- W4311139619 hasConceptScore W4311139619C178790620 @default.
- W4311139619 hasConceptScore W4311139619C179104552 @default.
- W4311139619 hasConceptScore W4311139619C185592680 @default.
- W4311139619 hasConceptScore W4311139619C191897082 @default.
- W4311139619 hasConceptScore W4311139619C192562407 @default.
- W4311139619 hasConceptScore W4311139619C2777581544 @default.
- W4311139619 hasConceptScore W4311139619C2779851234 @default.