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- W4311139678 abstract "The uncontrollable Li deposition and severe lithium polysulfide (LiPS) shuttling hinder the commercial application in lithium–sulfur (Li–S) batteries. Here, we propose a bifunctional electrolyte additive, 1,4-difluoroanthraquinone (DFAQ), to be used for lithium regulation and acceleration of sulfur redox kinetics. DFAQ is conducive to form a rigid and smooth LiF-rich organic–inorganic hybrid solid electrolyte interphase (SEI), realizing reversible Li plating/stripping, restraining dendrite growth, and shielding Li anode from the detrimental side reaction with LiPSs. More importantly, DFAQ can be used as a redox mediator to enable an oxygen radical-mediated catalytic cycle to dramatically promote the conversion of LiPSs. Accordingly, the Li–S battery with DFAQ demonstrates ultrahigh discharge capacities, enhanced high-rate performance, and outstanding long-cycle stability (1693.4 mAh g–1 at 0.5C over 700 cycles). Even under harsh conditions including high sulfur loading (5.8 mgS cm–2), ultrathin Li anode (50 μm), and low E/S ratio (5.0 μL mgS–1), the Li–S battery with DFAQ shows 80 cycles in comparison to just 30 cycles for control battery. This work demonstrates a facile additive strategy originated from bond chemistry to build applicable Li–S batteries." @default.
- W4311139678 created "2022-12-23" @default.
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- W4311139678 date "2022-12-09" @default.
- W4311139678 modified "2023-10-15" @default.
- W4311139678 title "Bifunctional Fluorinated Anthraquinone Additive for Improving Kinetics and Interfacial Chemistry in Rechargeable Li–S Batteries" @default.
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- W4311139678 doi "https://doi.org/10.1021/acsaem.2c03306" @default.
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