Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311151454> ?p ?o ?g. }
- W4311151454 endingPage "1802" @default.
- W4311151454 startingPage "1802" @default.
- W4311151454 abstract "The phenyltetrel pyridine-2-olates PhE(pyO)3 (E = Si, Ge, Sn; pyO = pyridine-2-olate) were synthesized from the respective chlorides PhECl3 and 2-hydroxypyridine (2-pyridone) with the aid of a sacrificial base (triethylamine). Their solid-state structures were determined by single-crystal X-ray diffraction. PhSi(pyO)3 exhibits a three-fold capped tetrahedral Si coordination sphere ([4+3]-coordination, Si···N separations ca. 3.0 Å), in accordance with structures of previously reported silicon pyridine-2-olates. PhGe(pyO)3 adopts a related [4+3]-coordination mode, which differs in terms of the tetrahedral faces capped by the pyridine N atoms. Additionally, shorter Ge···N separations (2.8–2.9 Å) indicate a trend toward tetrel hypercoordination. PhSn(pyO)3 features heptacoordinate tin within a pentagonal bipyramidal Sn coordination sphere (Sn···N separations 2.2–2.4 Å). For the Si and Sn compounds, 29Si and 119Sn NMR spectroscopy indicates retention of their tetrel coordination number in chloroform solution." @default.
- W4311151454 created "2022-12-23" @default.
- W4311151454 creator A5005708838 @default.
- W4311151454 creator A5008482759 @default.
- W4311151454 creator A5008660647 @default.
- W4311151454 date "2022-12-10" @default.
- W4311151454 modified "2023-10-01" @default.
- W4311151454 title "Molecular Structures of the Pyridine-2-olates PhE(pyO)3 (E = Si, Ge, Sn)—[4+3]-Coordination at Si, Ge vs. Heptacoordination at Sn" @default.
- W4311151454 cites W1481023260 @default.
- W4311151454 cites W1966235885 @default.
- W4311151454 cites W1985095903 @default.
- W4311151454 cites W1989353309 @default.
- W4311151454 cites W1990170643 @default.
- W4311151454 cites W1991531478 @default.
- W4311151454 cites W1996038995 @default.
- W4311151454 cites W2003138821 @default.
- W4311151454 cites W2014900162 @default.
- W4311151454 cites W2024175762 @default.
- W4311151454 cites W2028358200 @default.
- W4311151454 cites W2029523314 @default.
- W4311151454 cites W2035684154 @default.
- W4311151454 cites W2045118135 @default.
- W4311151454 cites W2045167623 @default.
- W4311151454 cites W2053355088 @default.
- W4311151454 cites W2059020082 @default.
- W4311151454 cites W2061360710 @default.
- W4311151454 cites W2066845252 @default.
- W4311151454 cites W2080234211 @default.
- W4311151454 cites W2084313351 @default.
- W4311151454 cites W2091203157 @default.
- W4311151454 cites W2094201786 @default.
- W4311151454 cites W2126383912 @default.
- W4311151454 cites W2131350133 @default.
- W4311151454 cites W2132454074 @default.
- W4311151454 cites W2145538332 @default.
- W4311151454 cites W2165400152 @default.
- W4311151454 cites W2166689829 @default.
- W4311151454 cites W2169508484 @default.
- W4311151454 cites W2316861270 @default.
- W4311151454 cites W2328165385 @default.
- W4311151454 cites W2331165243 @default.
- W4311151454 cites W2509430393 @default.
- W4311151454 cites W2513141335 @default.
- W4311151454 cites W2735194419 @default.
- W4311151454 cites W2763134411 @default.
- W4311151454 cites W2899396758 @default.
- W4311151454 cites W3015906512 @default.
- W4311151454 cites W3024446981 @default.
- W4311151454 cites W3040391881 @default.
- W4311151454 cites W3129096060 @default.
- W4311151454 cites W3140084777 @default.
- W4311151454 cites W4288439364 @default.
- W4311151454 doi "https://doi.org/10.3390/cryst12121802" @default.
- W4311151454 hasPublicationYear "2022" @default.
- W4311151454 type Work @default.
- W4311151454 citedByCount "4" @default.
- W4311151454 countsByYear W43111514542022 @default.
- W4311151454 countsByYear W43111514542023 @default.
- W4311151454 crossrefType "journal-article" @default.
- W4311151454 hasAuthorship W4311151454A5005708838 @default.
- W4311151454 hasAuthorship W4311151454A5008482759 @default.
- W4311151454 hasAuthorship W4311151454A5008660647 @default.
- W4311151454 hasBestOaLocation W43111514541 @default.
- W4311151454 hasConcept C11111787 @default.
- W4311151454 hasConcept C111592845 @default.
- W4311151454 hasConcept C115624301 @default.
- W4311151454 hasConcept C145148216 @default.
- W4311151454 hasConcept C155647269 @default.
- W4311151454 hasConcept C158842870 @default.
- W4311151454 hasConcept C178790620 @default.
- W4311151454 hasConcept C185592680 @default.
- W4311151454 hasConcept C2779485729 @default.
- W4311151454 hasConcept C2781283055 @default.
- W4311151454 hasConcept C33559828 @default.
- W4311151454 hasConcept C525849907 @default.
- W4311151454 hasConcept C544956773 @default.
- W4311151454 hasConcept C8010536 @default.
- W4311151454 hasConceptScore W4311151454C11111787 @default.
- W4311151454 hasConceptScore W4311151454C111592845 @default.
- W4311151454 hasConceptScore W4311151454C115624301 @default.
- W4311151454 hasConceptScore W4311151454C145148216 @default.
- W4311151454 hasConceptScore W4311151454C155647269 @default.
- W4311151454 hasConceptScore W4311151454C158842870 @default.
- W4311151454 hasConceptScore W4311151454C178790620 @default.
- W4311151454 hasConceptScore W4311151454C185592680 @default.
- W4311151454 hasConceptScore W4311151454C2779485729 @default.
- W4311151454 hasConceptScore W4311151454C2781283055 @default.
- W4311151454 hasConceptScore W4311151454C33559828 @default.
- W4311151454 hasConceptScore W4311151454C525849907 @default.
- W4311151454 hasConceptScore W4311151454C544956773 @default.
- W4311151454 hasConceptScore W4311151454C8010536 @default.
- W4311151454 hasIssue "12" @default.
- W4311151454 hasLocation W43111514541 @default.
- W4311151454 hasOpenAccess W4311151454 @default.
- W4311151454 hasPrimaryLocation W43111514541 @default.
- W4311151454 hasRelatedWork W1485279444 @default.
- W4311151454 hasRelatedWork W1972208387 @default.
- W4311151454 hasRelatedWork W2039854732 @default.