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- W4311166229 abstract "A highly enantioselective cascade carbonylation/annulation of benzyl bromides, CO, and vinyl benzoxazinanones under mild conditions has been established by Pd/chiral Lewis base relay catalysis, providing an efficient method to assemble chiral quinolinones from readily available starting materials in good yields with excellent diastereo- and enantioselectivities. The palladium catalyst plays two roles in this reaction, enabling both the carbonylation process and the generation of the zwitterionic π-allyl palladium intermediate." @default.
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- W4311166229 date "2022-12-12" @default.
- W4311166229 modified "2023-10-14" @default.
- W4311166229 title "Asymmetric Cascade Carbonylation/Annulation of Benzyl Bromides, CO, and Vinyl Benzoxazinanones Enabled by Pd/Chiral Lewis-Base Relay Catalysis" @default.
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- W4311166229 doi "https://doi.org/10.1021/acs.joc.2c02208" @default.
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