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- W4311194061 abstract "We report herein on a catalytic system involving palladium and copper to achieve the cyclization of N-arylcyanothioformamides and the synthesis of 2-cyanobenzothiazoles. The C-H functionalization/intramolecular C-S bond formation reaction was achieved in the presence of air, using 2.0 equiv of an inorganic additive (KI). In many cases, the reaction led to a sole product regioselectively obtained in good yields, allowing the synthesis of a wide range of substituted 2-cyanobenzothiazole derivatives, providing valuable building blocks for the design of more complex heterocyclic or molecular labeling systems." @default.
- W4311194061 created "2022-12-24" @default.
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- W4311194061 date "2022-12-01" @default.
- W4311194061 modified "2023-09-26" @default.
- W4311194061 title "Synthesis of 2-Cyanobenzothiazoles via Pd-Catalyzed/Cu-Assisted C-H Functionalization/Intramolecular C-S Bond Formation from N-Arylcyanothioformamides" @default.
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- W4311194061 doi "https://doi.org/10.3390/molecules27238426" @default.
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