FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311218482> ?p ?o ?g. }

• W4311218482 endingPage "156036" @default.
• W4311218482 startingPage "156036" @default.
• W4311218482 abstract "In this work, plasmonic monometallic Ag or Au nanoparticles (NPs) and bimetallic AuAg NPs supported on TiO2 with tunable bandgap structure were prepared by incipient impregnation method. Visible-light-driven photocatalytic oxidation of 5-hydroxymethylfurfural (5-HMF) to furandicarboxylic acid (FDCA) was used to evaluate their catalytic properties of the bimetallic catalysts. The incorporation of Au NPs into Ag NPs was capable of tuning their d-band centers to upshift toward the Fermi Level of the bimetallic catalysts, as evidenced by density function theory calculations and valence band XPS measurements. The bimetallic catalysts have narrower bandgap energies and better efficiencies in photogenerated charge separation and transfer, thus resulting in higher catalytic activities in the photocatalytic oxidation of HMF compared with the monometallic Au or Ag NPs catalyst. More interestingly, the monometallic Ag NPs catalyst only gave rise to an oxidized intermediate, i.e. 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), whereas the monometalic Au NPs and the bimetallic catalysts could afford FDCA because of their d-band center differences. The bimetallic catalysts also showed an excellent stability at least five successive runs in the photocatalytic oxidation of HMF to FDCA. This work offers a novel strategy for designing bimetallic catalysts used for the oxidation of 5-HMF to FDCA under visible light irradiation by mediating the d-band centers to upshift toward the Fermi Level." @default.
• W4311218482 created "2022-12-24" @default.
• W4311218482 creator A5021029773 @default.
• W4311218482 creator A5038788588 @default.
• W4311218482 creator A5073821538 @default.
• W4311218482 date "2023-03-01" @default.
• W4311218482 modified "2023-10-18" @default.
• W4311218482 title "Photocatalytic oxidation of 5-hydroxymethylfurfural to furandicarboxylic acid over the Au-Ag/TiO2 catalysts under visible light irradiation" @default.
• W4311218482 cites W1970127494 @default.
• W4311218482 cites W1981368803 @default.
• W4311218482 cites W2075130888 @default.
• W4311218482 cites W2079105963 @default.
• W4311218482 cites W2082684692 @default.
• W4311218482 cites W2087698390 @default.
• W4311218482 cites W2324176171 @default.
• W4311218482 cites W2328854581 @default.
• W4311218482 cites W2564427513 @default.
• W4311218482 cites W2592308660 @default.
• W4311218482 cites W2789725710 @default.
• W4311218482 cites W2793025954 @default.
• W4311218482 cites W2804364614 @default.
• W4311218482 cites W2810376782 @default.
• W4311218482 cites W2899373993 @default.
• W4311218482 cites W2917506622 @default.
• W4311218482 cites W2921151917 @default.
• W4311218482 cites W2944296961 @default.
• W4311218482 cites W3003713525 @default.
• W4311218482 cites W3007583150 @default.
• W4311218482 cites W3023954158 @default.
• W4311218482 cites W3024862761 @default.
• W4311218482 cites W3038134866 @default.
• W4311218482 cites W3038877406 @default.
• W4311218482 cites W3068146615 @default.
• W4311218482 cites W3082728285 @default.
• W4311218482 cites W3088285102 @default.
• W4311218482 cites W3091336126 @default.
• W4311218482 cites W3091588657 @default.
• W4311218482 cites W3097517630 @default.
• W4311218482 cites W3113584274 @default.
• W4311218482 cites W3125514521 @default.
• W4311218482 cites W3164648281 @default.
• W4311218482 cites W3165754888 @default.
• W4311218482 cites W3171556506 @default.
• W4311218482 cites W4210746485 @default.
• W4311218482 cites W4210853784 @default.
• W4311218482 cites W4213121893 @default.
• W4311218482 cites W4224239228 @default.
• W4311218482 cites W4225380152 @default.
• W4311218482 cites W4226374350 @default.
• W4311218482 cites W4226420527 @default.
• W4311218482 cites W4285255387 @default.
• W4311218482 cites W4293059872 @default.
• W4311218482 doi "https://doi.org/10.1016/j.apsusc.2022.156036" @default.
• W4311218482 hasPublicationYear "2023" @default.
• W4311218482 type Work @default.
• W4311218482 citedByCount "4" @default.
• W4311218482 countsByYear W43112184822023 @default.
• W4311218482 crossrefType "journal-article" @default.
• W4311218482 hasAuthorship W4311218482A5021029773 @default.
• W4311218482 hasAuthorship W4311218482A5038788588 @default.
• W4311218482 hasAuthorship W4311218482A5073821538 @default.
• W4311218482 hasConcept C104663316 @default.
• W4311218482 hasConcept C127413603 @default.
• W4311218482 hasConcept C155672457 @default.
• W4311218482 hasConcept C161790260 @default.
• W4311218482 hasConcept C171250308 @default.
• W4311218482 hasConcept C175708663 @default.
• W4311218482 hasConcept C178790620 @default.
• W4311218482 hasConcept C179104552 @default.
• W4311218482 hasConcept C185592680 @default.
• W4311218482 hasConcept C192562407 @default.
• W4311218482 hasConcept C42360764 @default.
• W4311218482 hasConcept C43411465 @default.
• W4311218482 hasConcept C49040817 @default.
• W4311218482 hasConcept C65165184 @default.
• W4311218482 hasConcept C75473681 @default.
• W4311218482 hasConceptScore W4311218482C104663316 @default.
• W4311218482 hasConceptScore W4311218482C127413603 @default.
• W4311218482 hasConceptScore W4311218482C155672457 @default.
• W4311218482 hasConceptScore W4311218482C161790260 @default.
• W4311218482 hasConceptScore W4311218482C171250308 @default.
• W4311218482 hasConceptScore W4311218482C175708663 @default.
• W4311218482 hasConceptScore W4311218482C178790620 @default.
• W4311218482 hasConceptScore W4311218482C179104552 @default.
• W4311218482 hasConceptScore W4311218482C185592680 @default.
• W4311218482 hasConceptScore W4311218482C192562407 @default.
• W4311218482 hasConceptScore W4311218482C42360764 @default.
• W4311218482 hasConceptScore W4311218482C43411465 @default.
• W4311218482 hasConceptScore W4311218482C49040817 @default.
• W4311218482 hasConceptScore W4311218482C65165184 @default.
• W4311218482 hasConceptScore W4311218482C75473681 @default.
• W4311218482 hasFunder F4320321001 @default.
• W4311218482 hasFunder F4320321605 @default.
• W4311218482 hasFunder F4320327780 @default.
• W4311218482 hasLocation W43112184821 @default.
• W4311218482 hasOpenAccess W4311218482 @default.
• W4311218482 hasPrimaryLocation W43112184821 @default.
• W4311218482 hasRelatedWork W1892382835 @default.

• next