FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311272529> ?p ?o ?g. }

• W4311272529 endingPage "23351" @default.
• W4311272529 startingPage "23340" @default.
• W4311272529 abstract "ZnO plays a very important role in many catalytic processes involving H2, yet the details on their interactions and H2 activation mechanism are still missing, owing to the lack of a characterization method that provides resolution at the atomic scale and follows the fate of oxide surface species. Here, we apply 17O solid-state NMR spectroscopy in combination with DFT calculations to unravel the surface structure of ZnO nanorods and explore the H2 activation process. We show that six different types of oxygen ions in the surface and subsurface of ZnO can be distinguished. H2 undergoes heterolytic dissociation on three-coordinated surface zinc and oxygen ions, while the formed hydride species migrate to nearby oxygen species, generating a second hydroxyl site. When oxygen vacancies are present, homolytic dissociation of H2 occurs and zinc hydride species form from the vacancies. Reaction mechanisms on oxide surfaces can be explored in a similar manner." @default.
• W4311272529 created "2022-12-25" @default.
• W4311272529 creator A5000330302 @default.
• W4311272529 creator A5002661071 @default.
• W4311272529 creator A5014202128 @default.
• W4311272529 creator A5015184109 @default.
• W4311272529 creator A5017364023 @default.
• W4311272529 creator A5018480960 @default.
• W4311272529 creator A5044490638 @default.
• W4311272529 creator A5049889103 @default.
• W4311272529 creator A5056867614 @default.
• W4311272529 creator A5066147502 @default.
• W4311272529 creator A5077254418 @default.
• W4311272529 creator A5082167565 @default.
• W4311272529 creator A5084735564 @default.
• W4311272529 creator A5085852346 @default.
• W4311272529 creator A5088420709 @default.
• W4311272529 creator A5089615110 @default.
• W4311272529 date "2022-12-13" @default.
• W4311272529 modified "2023-10-18" @default.
• W4311272529 title "Unveiling the Surface Structure of ZnO Nanorods and H₂ Activation Mechanisms with ¹⁷O NMR Spectroscopy" @default.
• W4311272529 cites W1965122909 @default.
• W4311272529 cites W1969754470 @default.
• W4311272529 cites W1970127494 @default.
• W4311272529 cites W1973358495 @default.
• W4311272529 cites W1981368803 @default.
• W4311272529 cites W1986731219 @default.
• W4311272529 cites W1988192951 @default.
• W4311272529 cites W1993130708 @default.
• W4311272529 cites W1995548022 @default.
• W4311272529 cites W2000940907 @default.
• W4311272529 cites W2003052069 @default.
• W4311272529 cites W2007395042 @default.
• W4311272529 cites W2011377242 @default.
• W4311272529 cites W2023224644 @default.
• W4311272529 cites W2042082708 @default.
• W4311272529 cites W2044986923 @default.
• W4311272529 cites W2053780344 @default.
• W4311272529 cites W2058877202 @default.
• W4311272529 cites W2060533155 @default.
• W4311272529 cites W2066350276 @default.
• W4311272529 cites W2069136237 @default.
• W4311272529 cites W2079808627 @default.
• W4311272529 cites W2080268376 @default.
• W4311272529 cites W2087698390 @default.
• W4311272529 cites W2096361495 @default.
• W4311272529 cites W2099470170 @default.
• W4311272529 cites W2122427541 @default.
• W4311272529 cites W2123153875 @default.
• W4311272529 cites W2124087099 @default.
• W4311272529 cites W2132872911 @default.
• W4311272529 cites W2136586839 @default.
• W4311272529 cites W2142388008 @default.
• W4311272529 cites W2154707832 @default.
• W4311272529 cites W2293193226 @default.
• W4311272529 cites W2321197966 @default.
• W4311272529 cites W2321711652 @default.
• W4311272529 cites W2323504704 @default.
• W4311272529 cites W2328378945 @default.
• W4311272529 cites W2396232752 @default.
• W4311272529 cites W2411623369 @default.
• W4311272529 cites W2529492055 @default.
• W4311272529 cites W2555763232 @default.
• W4311272529 cites W2600566292 @default.
• W4311272529 cites W2612231257 @default.
• W4311272529 cites W2753534401 @default.
• W4311272529 cites W2753887702 @default.
• W4311272529 cites W2755306577 @default.
• W4311272529 cites W2797646828 @default.
• W4311272529 cites W2804548876 @default.
• W4311272529 cites W2885149462 @default.
• W4311272529 cites W2906777646 @default.
• W4311272529 cites W2914844823 @default.
• W4311272529 cites W2944355614 @default.
• W4311272529 cites W2990609195 @default.
• W4311272529 cites W3016460444 @default.
• W4311272529 cites W3128218587 @default.
• W4311272529 cites W3214069988 @default.
• W4311272529 cites W3215554378 @default.
• W4311272529 cites W4206278439 @default.
• W4311272529 cites W4210348027 @default.
• W4311272529 cites W4210891477 @default.
• W4311272529 cites W4228999632 @default.
• W4311272529 cites W4231062228 @default.
• W4311272529 cites W4252958889 @default.
• W4311272529 cites W4280490875 @default.
• W4311272529 cites W4280505098 @default.
• W4311272529 doi "https://doi.org/10.1021/jacs.2c08356" @default.
• W4311272529 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36512749" @default.
• W4311272529 hasPublicationYear "2022" @default.
• W4311272529 type Work @default.
• W4311272529 citedByCount "4" @default.
• W4311272529 countsByYear W43112725292023 @default.
• W4311272529 crossrefType "journal-article" @default.
• W4311272529 hasAuthorship W4311272529A5000330302 @default.
• W4311272529 hasAuthorship W4311272529A5002661071 @default.
• W4311272529 hasAuthorship W4311272529A5014202128 @default.
• W4311272529 hasAuthorship W4311272529A5015184109 @default.

• next