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- W4311302334 endingPage "108069" @default.
- W4311302334 startingPage "108069" @default.
- W4311302334 abstract "Small-molecule hydrogels based on amino acid derivatives have promising applications in many biological fields, including cell culture, drug delivery, and tissue engineering. Although these hydrogels have been widely reported to have low cytotoxicity, biocompatibility, and tunable bioactivity, problems such as harsh preparation conditions and complex material design hinder their application. Herein, by adjusting pH to induce non-covalent interactions between small-molecule tryptophan derivatives (N-[(phenylmethoxy)carbonyl]-l-tryptophan, Mw: 338.35), we developed a self-assembled three-dimensional network hydrogel that can be rapidly formed in seconds. And the supramolecular self-assembly mechanism of the hydrogels was also investigated in detail through experimental characterizations and density functional theory calculation. As-prepared hydrogels also exhibit reversible pH-stimulated response and self-healing properties. This study details a research process for the simple and rapid preparation of tryptophan derivative-based hydrogels, which provides more reference ideas for the future development of materials based on other amino acid derivatives." @default.
- W4311302334 created "2022-12-25" @default.
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- W4311302334 date "2023-08-01" @default.
- W4311302334 modified "2023-10-18" @default.
- W4311302334 title "Build in seconds: Small-molecule hydrogels of self-assembled tryptophan derivatives" @default.
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- W4311302334 doi "https://doi.org/10.1016/j.cclet.2022.108069" @default.
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