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- W4311357971 abstract "For the purpose of broadening the understanding of the sulfonic acid coordination mechanism, a coordination system consisting of Eu(III) ion and 1,3,6,8-pyrene tetra-sulfonate (1,3,6,8-PTS) ligand was chosen as the typical research object. By step regulating the volume ratio of mixed solvents and the molar ratio of metal salts to ligands, two pyrene tetra-sulfonate europium coordination polymers, Eu6(μ6-O)(μ3-OH)8(NO3)6(1,3,6,8-H2PTS)(H2O)10 (1) and Eu(NO3)(1,3,6,8-PTS)0.5(H2O)3·0.5bipy (2), were obtained in sequence. Compound 1 shows a 1D chain-like structure interconnected with 1,3,6,8-PTS bridging ligands and rare [Eu6(μ6-O)(μ3-OH)8(NO3)6]2+ cluster nodes, while compound 2 shows a 2D layered structure. Further structural comparison with compound Eu(1,3,6,8-PTS)(H2O)7·4H2O·Hbipy (EuPTSbp-1) was discussed in detail and the structure formation mechanism was analyzed. On this basis, a sequential modulation strategy for pyrene tetra-sulfonate europium coordination polymers was proposed." @default.
- W4311357971 created "2022-12-25" @default.
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- W4311357971 date "2022-12-14" @default.
- W4311357971 modified "2023-10-16" @default.
- W4311357971 title "Two Novel Pyrene Tetra-Sulfonate Europium Coordination Polymers: Structure Formation Mechanism Analysis and Sequential Modulation Strategy" @default.
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- W4311357971 doi "https://doi.org/10.3390/cryst12121818" @default.
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