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• W4311365478 abstract "In this work, metal-organic framework MIL-101(Cr) with regular morphology, stable structure, and good dispersion was prepared by the hydrothermal method. MIL-101(Cr) has two different sizes of pores, but after TiO2 nanoparticles (NPs) were in situ prepared, the two pores disappear. The result demonstrates that TiO2 NPs were located in the pores of MIL-101(Cr). TiO2-decorated MIL-101(Cr) forms an inside type II heterojunction and the band gap energy is narrowed, which can promote electron-hole separation and enhance the light absorption. Therefore, the heterojunction shows a high visible light-induced peroxidase-like activity. Kinetic studies exhibit that the Km value of TiO2-in-MIL-101(Cr) to TMB is 0.17 mM, and the affinity of TiO2-in-MIL-101(Cr) is higher than that of natural horseradish peroxidase (HRP). Then, a turn-on colorimetric assay based on TiO2-in-MIL-101(Cr) was constructed for the detection of blood glucose. The detection range is 1-100 μM (R2 = 0.9950) with a limit of detection (LOD) of 1.17 μM. Compared with the clinical method, the constructed colorimetric method has accurate and reliable results for the clinical detection. The anti-interference experiment confirms that the method has high selectivity to glucose." @default.
• W4311365478 created "2022-12-25" @default.
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• W4311365478 date "2022-12-02" @default.
• W4311365478 modified "2023-10-01" @default.
• W4311365478 title "TiO₂-In-MIL-101(Cr) with Visible Light-Induced Peroxidase Activity for Colorimetric Detection of Blood Glucose" @default.
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• W4311365478 doi "https://doi.org/10.1021/acsomega.2c06176" @default.
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