Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311402858> ?p ?o ?g. }
- W4311402858 endingPage "159" @default.
- W4311402858 startingPage "146" @default.
- W4311402858 abstract "Ascribing to incremental fossil fuels emissions, the utilization and conversion of CO2 and development of renewable energy is globally essential and significative. Ultrathin 2D/2D heterojunctions with fast photo-generated electrons transmission channels illustrate a better strategy to improve photocatalytic activity. Herein, combing La2Ti2O7 with metallic few-layered Ti3C2 MXene to construct inter-plane 2D/2D heterojunction was in situ self-assembled through solvothermal method. Benefiting from the advantages including stability, conductivity, abundant active sites and formation of Schottky junctions, as expected, the ultrathin 2D/2D La2Ti2O7/Ti3C2 MXene nanosheets presented much improved photocatalytic ability for CO2 reduction to CO and CH4, which is about 4.6 and 11.4 times higher than that of mechanical mixed La2Ti2O7 and Ti3C2 MXene. fs-TAS and XPS provided direct evidence that the prominence of La2Ti2O7/Ti3C2 MXene in photocatalytic CO2 reduction reaction over other opponents should be attributed to the synergetic effect of efficient charge carrier mobility and formed 2D/2D Schottky heterojunction interfacial contact between La2Ti2O7 and Ti3C2 MXene. Intermediates revealed by in-situ DRIFTS and corresponding atomic-level DFT calculations confirmed the mechanism, pathways and selectivity for photocatalytic CO2 conversion. This work expanded promising prospects arouses new impetus for deepening the prehension of the mechanism of photocatalytic CO2 reduction, designing and fabrication of Schottky heterojunctions for application in conversion and utilization of CO2." @default.
- W4311402858 created "2022-12-26" @default.
- W4311402858 creator A5002141680 @default.
- W4311402858 creator A5008659449 @default.
- W4311402858 creator A5010465278 @default.
- W4311402858 creator A5016797703 @default.
- W4311402858 creator A5024493594 @default.
- W4311402858 creator A5026906414 @default.
- W4311402858 creator A5031815205 @default.
- W4311402858 creator A5059207044 @default.
- W4311402858 creator A5073593046 @default.
- W4311402858 creator A5091550889 @default.
- W4311402858 date "2023-01-01" @default.
- W4311402858 modified "2023-10-15" @default.
- W4311402858 title "Inter-plane 2D/2D ultrathin La2Ti2O7/Ti3C2 MXene Schottky heterojunctions toward high-efficiency photocatalytic CO2 reduction" @default.
- W4311402858 cites W1980704616 @default.
- W4311402858 cites W1988080928 @default.
- W4311402858 cites W2014780222 @default.
- W4311402858 cites W2015563866 @default.
- W4311402858 cites W2022085321 @default.
- W4311402858 cites W2028385867 @default.
- W4311402858 cites W2067452525 @default.
- W4311402858 cites W2069932293 @default.
- W4311402858 cites W2095543660 @default.
- W4311402858 cites W2127465043 @default.
- W4311402858 cites W2185780818 @default.
- W4311402858 cites W2342174548 @default.
- W4311402858 cites W2513142625 @default.
- W4311402858 cites W2563556731 @default.
- W4311402858 cites W2571933314 @default.
- W4311402858 cites W2588167716 @default.
- W4311402858 cites W2749561424 @default.
- W4311402858 cites W2759993421 @default.
- W4311402858 cites W2768038472 @default.
- W4311402858 cites W2792703666 @default.
- W4311402858 cites W2794677445 @default.
- W4311402858 cites W2802412693 @default.
- W4311402858 cites W2810050270 @default.
- W4311402858 cites W2884406729 @default.
- W4311402858 cites W2895278202 @default.
- W4311402858 cites W2896050259 @default.
- W4311402858 cites W2909675798 @default.
- W4311402858 cites W2910230156 @default.
- W4311402858 cites W2911133749 @default.
- W4311402858 cites W2936362817 @default.
- W4311402858 cites W2958082971 @default.
- W4311402858 cites W2963049339 @default.
- W4311402858 cites W2966082566 @default.
- W4311402858 cites W2971886594 @default.
- W4311402858 cites W2972777422 @default.
- W4311402858 cites W2984181348 @default.
- W4311402858 cites W2984228558 @default.
- W4311402858 cites W2993592145 @default.
- W4311402858 cites W2999761332 @default.
- W4311402858 cites W3011127673 @default.
- W4311402858 cites W3013838677 @default.
- W4311402858 cites W3016887752 @default.
- W4311402858 cites W3017221539 @default.
- W4311402858 cites W3026378869 @default.
- W4311402858 cites W3035307876 @default.
- W4311402858 cites W3036372824 @default.
- W4311402858 cites W3036413810 @default.
- W4311402858 cites W3037067499 @default.
- W4311402858 cites W3037248505 @default.
- W4311402858 cites W3044961500 @default.
- W4311402858 cites W3088764563 @default.
- W4311402858 cites W3093432062 @default.
- W4311402858 cites W3118498840 @default.
- W4311402858 cites W3118725028 @default.
- W4311402858 cites W3121406119 @default.
- W4311402858 cites W3128490736 @default.
- W4311402858 cites W3131402578 @default.
- W4311402858 cites W3137295689 @default.
- W4311402858 cites W3158674126 @default.
- W4311402858 cites W3160633661 @default.
- W4311402858 cites W3168832170 @default.
- W4311402858 cites W3184197505 @default.
- W4311402858 cites W3194010504 @default.
- W4311402858 cites W3196636719 @default.
- W4311402858 cites W3197427103 @default.
- W4311402858 cites W3198176550 @default.
- W4311402858 cites W3199952910 @default.
- W4311402858 cites W3201187921 @default.
- W4311402858 cites W3204153005 @default.
- W4311402858 cites W3209154883 @default.
- W4311402858 cites W3211349002 @default.
- W4311402858 cites W4205958797 @default.
- W4311402858 cites W4206550725 @default.
- W4311402858 cites W4210489538 @default.
- W4311402858 cites W4220996428 @default.
- W4311402858 cites W4251102459 @default.
- W4311402858 cites W4281257664 @default.
- W4311402858 doi "https://doi.org/10.1016/s1872-2067(22)64155-x" @default.
- W4311402858 hasPublicationYear "2023" @default.
- W4311402858 type Work @default.
- W4311402858 citedByCount "11" @default.
- W4311402858 countsByYear W43114028582023 @default.
- W4311402858 crossrefType "journal-article" @default.