FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311446779> ?p ?o ?g. }

• W4311446779 endingPage "35" @default.
• W4311446779 startingPage "26" @default.
• W4311446779 abstract "While low-cost natural gas remains abundant, the energy content of this fuel can be utilized without greenhouse gas emissions through the production of molecular hydrogen and solid carbon via methane pyrolysis. In the absence of a carbon tax, methane pyrolysis is not economically competitive with current hydrogen production methods unless the carbon byproducts can be valorized. In this work, we assess the viability of the carbon byproduct produced from methane pyrolysis in molten salts as high-value-added anode or conductive additive for secondary Li-ion and Na-ion batteries. Raman characterization and electrochemical differential capacity analysis demonstrate that the use of molten salt mixtures with catalytically-active FeCl3-or MnCl2 result in more graphitic carbon co-products. These graphitic carbons exhibit the best electrochemical performance (up to 272 mAh/g of reversible capacity) when used as Li-ion anodes. For all carbon samples studied here, disordered carbon domains and retained salt species trapped and/or intercalated into the carbon structure were identified by X-ray photoelectron and multinuclear solid-state nuclear magnetic resonance spectroscopy. The latter lead to reduced electrochemical activity and reversibility, and poorer rate performance compared to commercial carbon anodes. The electronic conductivity of the pyrolyzed carbons is found to be highly dependent on their purity, with the purest carbon exhibiting an electronic conductivity nearly on par with that of commercial carbon additives. These findings suggest that more effective removal of the salt catalyst could enable applications of these carbons in secondary batteries, providing a financial incentive for the large-scale implementation of methane pyrolysis for “low-carbon” hydrogen production." @default.
• W4311446779 created "2022-12-26" @default.
• W4311446779 creator A5016111292 @default.
• W4311446779 creator A5023722063 @default.
• W4311446779 creator A5037680218 @default.
• W4311446779 creator A5039849587 @default.
• W4311446779 creator A5041154391 @default.
• W4311446779 creator A5042082931 @default.
• W4311446779 creator A5048737035 @default.
• W4311446779 creator A5074009012 @default.
• W4311446779 creator A5081341837 @default.
• W4311446779 date "2023-02-01" @default.
• W4311446779 modified "2023-10-06" @default.
• W4311446779 title "Valorizing the carbon byproduct of methane pyrolysis in batteries" @default.
• W4311446779 cites W1967712272 @default.
• W4311446779 cites W1996111706 @default.
• W4311446779 cites W2003525480 @default.
• W4311446779 cites W2003843039 @default.
• W4311446779 cites W2006612611 @default.
• W4311446779 cites W2007114372 @default.
• W4311446779 cites W2007602879 @default.
• W4311446779 cites W2009419703 @default.
• W4311446779 cites W2010719723 @default.
• W4311446779 cites W2012995907 @default.
• W4311446779 cites W2017177900 @default.
• W4311446779 cites W2018651936 @default.
• W4311446779 cites W2018735453 @default.
• W4311446779 cites W2025010304 @default.
• W4311446779 cites W2025084334 @default.
• W4311446779 cites W2040531064 @default.
• W4311446779 cites W2041880084 @default.
• W4311446779 cites W2042581501 @default.
• W4311446779 cites W2043898187 @default.
• W4311446779 cites W2044889937 @default.
• W4311446779 cites W2047506023 @default.
• W4311446779 cites W2051894667 @default.
• W4311446779 cites W2068056110 @default.
• W4311446779 cites W2070006044 @default.
• W4311446779 cites W2080334952 @default.
• W4311446779 cites W2087656378 @default.
• W4311446779 cites W2090550478 @default.
• W4311446779 cites W2099633492 @default.
• W4311446779 cites W2103492987 @default.
• W4311446779 cites W2103581458 @default.
• W4311446779 cites W2167590372 @default.
• W4311446779 cites W2243354830 @default.
• W4311446779 cites W2258819372 @default.
• W4311446779 cites W2313083925 @default.
• W4311446779 cites W2323883417 @default.
• W4311446779 cites W2335650612 @default.
• W4311446779 cites W2341599652 @default.
• W4311446779 cites W2402743136 @default.
• W4311446779 cites W2523751181 @default.
• W4311446779 cites W2559524781 @default.
• W4311446779 cites W2591042472 @default.
• W4311446779 cites W2594391820 @default.
• W4311446779 cites W2754500944 @default.
• W4311446779 cites W2769191683 @default.
• W4311446779 cites W2772204860 @default.
• W4311446779 cites W2782500965 @default.
• W4311446779 cites W2783603984 @default.
• W4311446779 cites W2897415506 @default.
• W4311446779 cites W2898023879 @default.
• W4311446779 cites W2910803183 @default.
• W4311446779 cites W2911588662 @default.
• W4311446779 cites W2944612620 @default.
• W4311446779 cites W2944993625 @default.
• W4311446779 cites W2968284787 @default.
• W4311446779 cites W2971741429 @default.
• W4311446779 cites W2982727982 @default.
• W4311446779 cites W2984501898 @default.
• W4311446779 cites W3032859978 @default.
• W4311446779 cites W3037044448 @default.
• W4311446779 cites W3094504755 @default.
• W4311446779 cites W3109231866 @default.
• W4311446779 cites W3110074893 @default.
• W4311446779 cites W3114200504 @default.
• W4311446779 cites W3118089531 @default.
• W4311446779 cites W3208127462 @default.
• W4311446779 cites W37502045 @default.
• W4311446779 cites W4200429148 @default.
• W4311446779 cites W4211102859 @default.
• W4311446779 doi "https://doi.org/10.1016/j.carbon.2022.12.044" @default.
• W4311446779 hasPublicationYear "2023" @default.
• W4311446779 type Work @default.
• W4311446779 citedByCount "8" @default.
• W4311446779 countsByYear W43114467792023 @default.
• W4311446779 crossrefType "journal-article" @default.
• W4311446779 hasAuthorship W4311446779A5016111292 @default.
• W4311446779 hasAuthorship W4311446779A5023722063 @default.
• W4311446779 hasAuthorship W4311446779A5037680218 @default.
• W4311446779 hasAuthorship W4311446779A5039849587 @default.
• W4311446779 hasAuthorship W4311446779A5041154391 @default.
• W4311446779 hasAuthorship W4311446779A5042082931 @default.
• W4311446779 hasAuthorship W4311446779A5048737035 @default.
• W4311446779 hasAuthorship W4311446779A5074009012 @default.
• W4311446779 hasAuthorship W4311446779A5081341837 @default.
• W4311446779 hasBestOaLocation W43114467791 @default.

• next