Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311451159> ?p ?o ?g. }
- W4311451159 endingPage "16252" @default.
- W4311451159 startingPage "16241" @default.
- W4311451159 abstract "Oxidative coupling of hydroxycinnamoylagmatines in barley (Hordeum vulgare) and related Hordeum species is part of the plant defense mechanism. Three linkage types have been reported for hydroxycinnamoylagmatine dimers, but knowledge on oxidative coupling reactions underlying their formation is limited. In this study, the monomers coumaroylagmatine, feruloylagmatine, and sinapoylagmatine were each incubated with horseradish peroxidase. Their coupling reactivity was in line with the order of peak potentials measured: sinapoylagmatine (245 mV) > feruloylagmatine (341 mV) > coumaroylagmatine (506 mV). Structure elucidation of fourteen in vitro coupling products by NMR and MS revealed that the three main linkage types were identical to those naturally present in Hordeum species, namely, 4-O-7'/3-8', 2-7'/8-8', and 8-8'/9-N-7'. Furthermore, we identified two linkage types that were not previously reported for hydroxycinnamoylagmatine dimers, namely, 8-8' and 4-O-8'. We conclude that oxidative coupling by horseradish peroxidase can be used for biomimetic formation of natural antifungal hydroxycinnamoylagmatine dimers from barley." @default.
- W4311451159 created "2022-12-26" @default.
- W4311451159 creator A5010469680 @default.
- W4311451159 creator A5016397696 @default.
- W4311451159 creator A5059821168 @default.
- W4311451159 creator A5080014856 @default.
- W4311451159 creator A5086831549 @default.
- W4311451159 date "2022-12-14" @default.
- W4311451159 modified "2023-09-26" @default.
- W4311451159 title "Biomimetic Enzymatic Oxidative Coupling of Barley Phenolamides: Hydroxycinnamoylagmatines" @default.
- W4311451159 cites W1973780654 @default.
- W4311451159 cites W1983056389 @default.
- W4311451159 cites W1990330049 @default.
- W4311451159 cites W1992807322 @default.
- W4311451159 cites W1998026351 @default.
- W4311451159 cites W2002086702 @default.
- W4311451159 cites W2008971732 @default.
- W4311451159 cites W2012651448 @default.
- W4311451159 cites W2014705166 @default.
- W4311451159 cites W2017277194 @default.
- W4311451159 cites W2018812226 @default.
- W4311451159 cites W2028788686 @default.
- W4311451159 cites W2033008243 @default.
- W4311451159 cites W2042174332 @default.
- W4311451159 cites W2047559951 @default.
- W4311451159 cites W2071415044 @default.
- W4311451159 cites W2074811222 @default.
- W4311451159 cites W2086798229 @default.
- W4311451159 cites W2090083047 @default.
- W4311451159 cites W2094648998 @default.
- W4311451159 cites W2103603825 @default.
- W4311451159 cites W2164940935 @default.
- W4311451159 cites W2238286371 @default.
- W4311451159 cites W2317502363 @default.
- W4311451159 cites W2331905856 @default.
- W4311451159 cites W2616022251 @default.
- W4311451159 cites W3023362451 @default.
- W4311451159 cites W3027915163 @default.
- W4311451159 cites W3117895167 @default.
- W4311451159 cites W3147758644 @default.
- W4311451159 cites W4221113988 @default.
- W4311451159 doi "https://doi.org/10.1021/acs.jafc.2c07457" @default.
- W4311451159 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36516832" @default.
- W4311451159 hasPublicationYear "2022" @default.
- W4311451159 type Work @default.
- W4311451159 citedByCount "1" @default.
- W4311451159 countsByYear W43114511592023 @default.
- W4311451159 crossrefType "journal-article" @default.
- W4311451159 hasAuthorship W4311451159A5010469680 @default.
- W4311451159 hasAuthorship W4311451159A5016397696 @default.
- W4311451159 hasAuthorship W4311451159A5059821168 @default.
- W4311451159 hasAuthorship W4311451159A5080014856 @default.
- W4311451159 hasAuthorship W4311451159A5086831549 @default.
- W4311451159 hasBestOaLocation W43114511591 @default.
- W4311451159 hasConcept C161790260 @default.
- W4311451159 hasConcept C162008176 @default.
- W4311451159 hasConcept C181199279 @default.
- W4311451159 hasConcept C185592680 @default.
- W4311451159 hasConcept C2777676563 @default.
- W4311451159 hasConcept C2993665447 @default.
- W4311451159 hasConcept C46757340 @default.
- W4311451159 hasConcept C55493867 @default.
- W4311451159 hasConcept C57600042 @default.
- W4311451159 hasConcept C59822182 @default.
- W4311451159 hasConcept C71240020 @default.
- W4311451159 hasConcept C83155894 @default.
- W4311451159 hasConcept C86803240 @default.
- W4311451159 hasConceptScore W4311451159C161790260 @default.
- W4311451159 hasConceptScore W4311451159C162008176 @default.
- W4311451159 hasConceptScore W4311451159C181199279 @default.
- W4311451159 hasConceptScore W4311451159C185592680 @default.
- W4311451159 hasConceptScore W4311451159C2777676563 @default.
- W4311451159 hasConceptScore W4311451159C2993665447 @default.
- W4311451159 hasConceptScore W4311451159C46757340 @default.
- W4311451159 hasConceptScore W4311451159C55493867 @default.
- W4311451159 hasConceptScore W4311451159C57600042 @default.
- W4311451159 hasConceptScore W4311451159C59822182 @default.
- W4311451159 hasConceptScore W4311451159C71240020 @default.
- W4311451159 hasConceptScore W4311451159C83155894 @default.
- W4311451159 hasConceptScore W4311451159C86803240 @default.
- W4311451159 hasFunder F4320321800 @default.
- W4311451159 hasIssue "51" @default.
- W4311451159 hasLocation W43114511591 @default.
- W4311451159 hasLocation W43114511592 @default.
- W4311451159 hasLocation W43114511593 @default.
- W4311451159 hasOpenAccess W4311451159 @default.
- W4311451159 hasPrimaryLocation W43114511591 @default.
- W4311451159 hasRelatedWork W1152439734 @default.
- W4311451159 hasRelatedWork W1963835436 @default.
- W4311451159 hasRelatedWork W1974097689 @default.
- W4311451159 hasRelatedWork W1975997521 @default.
- W4311451159 hasRelatedWork W2463405247 @default.
- W4311451159 hasRelatedWork W2533405060 @default.
- W4311451159 hasRelatedWork W2592360891 @default.
- W4311451159 hasRelatedWork W2734299916 @default.
- W4311451159 hasRelatedWork W2744364675 @default.
- W4311451159 hasRelatedWork W2035103816 @default.
- W4311451159 hasVolume "70" @default.