Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311453059> ?p ?o ?g. }
- W4311453059 endingPage "221" @default.
- W4311453059 startingPage "214" @default.
- W4311453059 abstract "Rh-based catalysts are widely used in CO hydrogenation to ethanol. In this work, Rh/TiO2 catalysts were prepared by glow discharge plasma. Rhodium salt was reduced by electrons in an electric field at room temperature. Oxygen vacancies and Ti3+ were produced on the surface of Rh/TiO2 by plasma. The defects promoted the synergistic effect of Rh and TiO2 through the enhanced interaction between active metal and supporter. Ti3+ is beneficial for the adsorption of intermediate formyl group. In situ IR revealed that the bridged and linear adsorption mechanisms of CO can promote the formation of ethanol intermediates. Rh/TiO2 catalysts by plasma exhibited a superior space-time yield of 0.106 gMeOH·gcat–1 h–1, at 260 °C and 3 MPa, which was approximately 1.8 times that by traditional hydrogen reduction." @default.
- W4311453059 created "2022-12-26" @default.
- W4311453059 creator A5012983440 @default.
- W4311453059 creator A5017777141 @default.
- W4311453059 creator A5036854394 @default.
- W4311453059 creator A5054751760 @default.
- W4311453059 date "2022-12-14" @default.
- W4311453059 modified "2023-10-16" @default.
- W4311453059 title "Introducing Oxygen Vacancies and Ti<sup>3+</sup> on Rh/TiO<sub>2</sub> via Plasma Treatment for CO Hydrogenation to Ethanol" @default.
- W4311453059 cites W1996879791 @default.
- W4311453059 cites W1997537926 @default.
- W4311453059 cites W2017458386 @default.
- W4311453059 cites W2041890295 @default.
- W4311453059 cites W2043574483 @default.
- W4311453059 cites W2044287746 @default.
- W4311453059 cites W2054854717 @default.
- W4311453059 cites W2055386297 @default.
- W4311453059 cites W2057340677 @default.
- W4311453059 cites W2059616454 @default.
- W4311453059 cites W2088717848 @default.
- W4311453059 cites W2089095241 @default.
- W4311453059 cites W2090710257 @default.
- W4311453059 cites W2133819377 @default.
- W4311453059 cites W2138872642 @default.
- W4311453059 cites W2140405200 @default.
- W4311453059 cites W2188192921 @default.
- W4311453059 cites W2212674613 @default.
- W4311453059 cites W2298984617 @default.
- W4311453059 cites W2417161969 @default.
- W4311453059 cites W2470528415 @default.
- W4311453059 cites W2478757962 @default.
- W4311453059 cites W2567145470 @default.
- W4311453059 cites W2600737316 @default.
- W4311453059 cites W2642691642 @default.
- W4311453059 cites W2792748896 @default.
- W4311453059 cites W2805573727 @default.
- W4311453059 cites W2808080254 @default.
- W4311453059 cites W2916844983 @default.
- W4311453059 cites W2939488989 @default.
- W4311453059 cites W2952234137 @default.
- W4311453059 cites W3002002626 @default.
- W4311453059 cites W3021794775 @default.
- W4311453059 cites W3095677732 @default.
- W4311453059 cites W3135790468 @default.
- W4311453059 cites W3184826174 @default.
- W4311453059 cites W3194089424 @default.
- W4311453059 cites W3205959228 @default.
- W4311453059 cites W3209778493 @default.
- W4311453059 cites W3217154064 @default.
- W4311453059 cites W4213135353 @default.
- W4311453059 cites W4224281018 @default.
- W4311453059 doi "https://doi.org/10.1021/acs.energyfuels.2c03018" @default.
- W4311453059 hasPublicationYear "2022" @default.
- W4311453059 type Work @default.
- W4311453059 citedByCount "1" @default.
- W4311453059 crossrefType "journal-article" @default.
- W4311453059 hasAuthorship W4311453059A5012983440 @default.
- W4311453059 hasAuthorship W4311453059A5017777141 @default.
- W4311453059 hasAuthorship W4311453059A5036854394 @default.
- W4311453059 hasAuthorship W4311453059A5054751760 @default.
- W4311453059 hasConcept C134121241 @default.
- W4311453059 hasConcept C13965031 @default.
- W4311453059 hasConcept C147789679 @default.
- W4311453059 hasConcept C150394285 @default.
- W4311453059 hasConcept C161790260 @default.
- W4311453059 hasConcept C178790620 @default.
- W4311453059 hasConcept C179104552 @default.
- W4311453059 hasConcept C185592680 @default.
- W4311453059 hasConcept C191897082 @default.
- W4311453059 hasConcept C192562407 @default.
- W4311453059 hasConcept C512968161 @default.
- W4311453059 hasConcept C521398313 @default.
- W4311453059 hasConcept C540031477 @default.
- W4311453059 hasConcept C544153396 @default.
- W4311453059 hasConceptScore W4311453059C134121241 @default.
- W4311453059 hasConceptScore W4311453059C13965031 @default.
- W4311453059 hasConceptScore W4311453059C147789679 @default.
- W4311453059 hasConceptScore W4311453059C150394285 @default.
- W4311453059 hasConceptScore W4311453059C161790260 @default.
- W4311453059 hasConceptScore W4311453059C178790620 @default.
- W4311453059 hasConceptScore W4311453059C179104552 @default.
- W4311453059 hasConceptScore W4311453059C185592680 @default.
- W4311453059 hasConceptScore W4311453059C191897082 @default.
- W4311453059 hasConceptScore W4311453059C192562407 @default.
- W4311453059 hasConceptScore W4311453059C512968161 @default.
- W4311453059 hasConceptScore W4311453059C521398313 @default.
- W4311453059 hasConceptScore W4311453059C540031477 @default.
- W4311453059 hasConceptScore W4311453059C544153396 @default.
- W4311453059 hasFunder F4320321001 @default.
- W4311453059 hasFunder F4320321540 @default.
- W4311453059 hasIssue "1" @default.
- W4311453059 hasLocation W43114530591 @default.
- W4311453059 hasOpenAccess W4311453059 @default.
- W4311453059 hasPrimaryLocation W43114530591 @default.
- W4311453059 hasRelatedWork W2006471732 @default.
- W4311453059 hasRelatedWork W2010422626 @default.
- W4311453059 hasRelatedWork W2080852327 @default.
- W4311453059 hasRelatedWork W2132093514 @default.