Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311453588> ?p ?o ?g. }
- W4311453588 abstract "Abstract Heterocycles containing group 13 and 15 elements such as borazines are an integral part of organic, biomedical and materials chemistry. Surprisingly, heterocycles containing P and Al are rare. We have now utilized phosphaalumenes in reactions with alkynes, alkenes and conjugated double bond systems. With sterically demanding alkynes 1,2‐phosphaalumetes were afforded, whereas the reaction with HCCH or HCCSiMe 3 gave 1,4‐phosphaaluminabarrelenes. Using styrene saturated 1,2‐phosphaalumates were formed, which reacted further with additional styrene to give different regio‐isomers of 1,4‐aluminaphosphorinanes. Using ethylene, a 1,4‐aluminaphosphorinane is obtained, while with 1,3‐butadiene a bicyclic system containing an aluminacyclopentane and a phosphirane unit was synthesized. The experimental work is supported by theoretical studies to shed light on the mechanism governing the formation of these heterocycles." @default.
- W4311453588 created "2022-12-26" @default.
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- W4311453588 date "2023-01-25" @default.
- W4311453588 modified "2023-10-01" @default.
- W4311453588 title "On the Reactivity of Phosphaalumenes towards C−C Multiple Bonds" @default.
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- W4311453588 doi "https://doi.org/10.1002/anie.202215838" @default.
- W4311453588 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36516342" @default.
- W4311453588 hasPublicationYear "2023" @default.
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