FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311458213> ?p ?o ?g. }

• W4311458213 endingPage "193" @default.
• W4311458213 startingPage "185" @default.
• W4311458213 abstract "Atomically precise heterometallic clusters constitute a new family of model catalysts for understanding the fundamental catalysis process widely occurred in supported nanocatalysts, however, their syntheses and structure/composition modulations are nonetheless daunting challenges. Herein, three novel heterometallic Ag/Ti clusters with different Ag-doping ratios, Ag4Ti14, Ag4Ti6 and Ag4Ti2, have been readily synthesized in decagram-scale quantities through ligand engineering strategy. Thereinto, Ag4Ti2 can be efficiently prepared within 3 h in a quite high yield > 95 %. More remarkably, Ag4Ti2 shows unprecedented catalytic activity (>90 % conversion within 1 min) and selectivity (nearly 100 %) towards oxidation of thioethers with a wide substrate scope even including notorious 2-chloroethyl ethyl sulfide (CEES) at room temperature (turnover frequency = 11,880 h−1), which is mainly attributed to its full-surface-exposure-doping Ag atoms (affinity for binding of substrate) on TiO support and their cooperativity, whereas the other two are not the same case. Moreover, the Ag4Ti2 is highly robust in catalysis process and can be readily recovered and reused at least six cycles without observable loss of activity and selectivity, enabling this cluster hold great promise in industrial applications. This work not only establishes a general method to scale-up synthesis of Ag/Ti clusters but also provides an atom-precise model catalyst to understand the structure–property correlations of real-world conventional nanocatalysts such as silver doped-TiO2 nanoparticles." @default.
• W4311458213 created "2022-12-26" @default.
• W4311458213 creator A5002580982 @default.
• W4311458213 creator A5005616359 @default.
• W4311458213 creator A5018121887 @default.
• W4311458213 creator A5026286216 @default.
• W4311458213 creator A5031380067 @default.
• W4311458213 creator A5062298428 @default.
• W4311458213 creator A5080922192 @default.
• W4311458213 date "2023-01-01" @default.
• W4311458213 modified "2023-10-14" @default.
• W4311458213 title "Decagram-scale synthesis of heterometallic Ag/Ti cluster as sustainable catalyst for selective oxidation of sulfides" @default.
• W4311458213 cites W1807074700 @default.
• W4311458213 cites W1963666932 @default.
• W4311458213 cites W1966857466 @default.
• W4311458213 cites W1969360633 @default.
• W4311458213 cites W1981152059 @default.
• W4311458213 cites W1997136694 @default.
• W4311458213 cites W2022504800 @default.
• W4311458213 cites W2045933640 @default.
• W4311458213 cites W2058516595 @default.
• W4311458213 cites W2059205366 @default.
• W4311458213 cites W2077247037 @default.
• W4311458213 cites W2084648663 @default.
• W4311458213 cites W2134334430 @default.
• W4311458213 cites W2136852491 @default.
• W4311458213 cites W2145538332 @default.
• W4311458213 cites W2165528549 @default.
• W4311458213 cites W2170376650 @default.
• W4311458213 cites W2178087656 @default.
• W4311458213 cites W2193378402 @default.
• W4311458213 cites W2204425562 @default.
• W4311458213 cites W2295691216 @default.
• W4311458213 cites W2316790082 @default.
• W4311458213 cites W2321841885 @default.
• W4311458213 cites W2332455332 @default.
• W4311458213 cites W2335043886 @default.
• W4311458213 cites W2538094194 @default.
• W4311458213 cites W2607034702 @default.
• W4311458213 cites W2610281118 @default.
• W4311458213 cites W2611428423 @default.
• W4311458213 cites W2745844311 @default.
• W4311458213 cites W2746937138 @default.
• W4311458213 cites W2770965322 @default.
• W4311458213 cites W2802911519 @default.
• W4311458213 cites W2803353396 @default.
• W4311458213 cites W2816613743 @default.
• W4311458213 cites W2898516497 @default.
• W4311458213 cites W2901109410 @default.
• W4311458213 cites W2902687065 @default.
• W4311458213 cites W2903712155 @default.
• W4311458213 cites W2918199345 @default.
• W4311458213 cites W2947748250 @default.
• W4311458213 cites W2955337945 @default.
• W4311458213 cites W2965398811 @default.
• W4311458213 cites W2969763483 @default.
• W4311458213 cites W2979870049 @default.
• W4311458213 cites W2981755571 @default.
• W4311458213 cites W2989636128 @default.
• W4311458213 cites W3012501552 @default.
• W4311458213 cites W3037934152 @default.
• W4311458213 cites W3045562383 @default.
• W4311458213 cites W3089133704 @default.
• W4311458213 cites W3108944117 @default.
• W4311458213 cites W3111402296 @default.
• W4311458213 cites W3147813353 @default.
• W4311458213 cites W3190615594 @default.
• W4311458213 cites W3199690145 @default.
• W4311458213 cites W3210404838 @default.
• W4311458213 cites W4200421103 @default.
• W4311458213 cites W4200535306 @default.
• W4311458213 cites W4211240100 @default.
• W4311458213 cites W4234750540 @default.
• W4311458213 doi "https://doi.org/10.1016/j.jcat.2022.12.007" @default.
• W4311458213 hasPublicationYear "2023" @default.
• W4311458213 type Work @default.
• W4311458213 citedByCount "4" @default.
• W4311458213 countsByYear W43114582132023 @default.
• W4311458213 crossrefType "journal-article" @default.
• W4311458213 hasAuthorship W4311458213A5002580982 @default.
• W4311458213 hasAuthorship W4311458213A5005616359 @default.
• W4311458213 hasAuthorship W4311458213A5018121887 @default.
• W4311458213 hasAuthorship W4311458213A5026286216 @default.
• W4311458213 hasAuthorship W4311458213A5031380067 @default.
• W4311458213 hasAuthorship W4311458213A5062298428 @default.
• W4311458213 hasAuthorship W4311458213A5080922192 @default.
• W4311458213 hasConcept C111368507 @default.
• W4311458213 hasConcept C116569031 @default.
• W4311458213 hasConcept C118792377 @default.
• W4311458213 hasConcept C127313418 @default.
• W4311458213 hasConcept C127413603 @default.
• W4311458213 hasConcept C134121241 @default.
• W4311458213 hasConcept C155672457 @default.
• W4311458213 hasConcept C161790260 @default.
• W4311458213 hasConcept C164866538 @default.
• W4311458213 hasConcept C166014724 @default.
• W4311458213 hasConcept C170493617 @default.
• W4311458213 hasConcept C171250308 @default.

• next