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- W4311484909 abstract "The design of molecular containers capable of selectively binding specific guest molecules presents an interesting synthetic challenge in supramolecular chemistry. Here, we report the synthesis and structure of a coordination cage assembled from Cu3I4− clusters and tripodal cationic N-donor ligands. Owing to the localized permanent charges in the ligand core the cage binds iodide anions in specific regions within the cage through ionic interactions. This allows the selective binding of bromomethanes as secondary guest species within the cage promoted by halogen bonding, which was confirmed by single-crystal X-ray diffraction." @default.
- W4311484909 created "2022-12-26" @default.
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- W4311484909 date "2023-01-11" @default.
- W4311484909 modified "2023-10-10" @default.
- W4311484909 title "Charge‐Assisted Halogen Bonding in an Ionic Cavity of a Coordination Cage Based on a Copper(I) Iodide Cluster" @default.
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- W4311484909 doi "https://doi.org/10.1002/ange.202215689" @default.
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