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- W4311489122 abstract "The understanding of intrinsic kinetics was crucial in guiding reactor design. However, the intrinsic kinetics of catalytic hydrogenation of p-nitroanisole (PNA) to p-aminoanisole remains obscure. In this work, the kinetic characteristics were experimentally and theoretically investigated under various experimental conditions. From the power law analysis of the initial reaction rate, the reaction order was found to be from 0.34 (at 343 K) to 0.53 (at 353 K) for hydrogen and 0.31∼ 0.34 for PNA (at concentrations less than 90 g·L−1), while the reaction was considered to be zero-order under higher PNA concentration (>90 g·L−1). The data was also used to fit Eley-Rideal and Langmuir-Hinshelwood-Hougen-Watson (LHHW) models. It was found that the rate-controlling step was the adsorption of dual-site dissociative H2 based on LHHW model. The accuracy of the screened model was verified by correlation, between the predicted data and experimental data. This study could provide significant guidance for the hydrogenation reaction and reactor." @default.
- W4311489122 created "2022-12-26" @default.
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- W4311489122 date "2023-02-01" @default.
- W4311489122 modified "2023-10-14" @default.
- W4311489122 title "Catalytic hydrogenation of p-nitroanisole over Raney nickel for p-aminoanisole synthesis: Intrinsic kinetics studies" @default.
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- W4311489122 doi "https://doi.org/10.1016/j.cherd.2022.12.011" @default.
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