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- W4311494562 abstract "Abstract. The near-infrared (NIR) spectra of hydrous minerals display absorption bands involving multiple excitations of vibrational modes. They usually involve OH stretching modes, but their interpretation is not straightforward due to the combined effects of bond anharmonicity and vibrational coupling. In the present study, the mid-infrared (MIR) and near-infrared spectra of well-ordered samples of trioctahedral layered hydrous minerals, talc, brucite and lizardite, have been measured on a spectral range extending from the fundamental vibrational modes to the second OH stretching overtones. The bands corresponding to molecular overtones are interpreted using an effective approach allowing us to infer the anharmonicity and coupling parameters controlling the OH stretching frequencies from spectroscopic data. They follow the usual relation between transition energy and quantum number of the excited state, which facilitates the comparison of NIR and MIR spectra. The results support the assignment of the main overtone bands to specific environments of OH groups and bring new constraints for the identification of the vibrational bands related to Fe and Al substitutions at octahedral sites in serpentines. The two-phonon absorption bands are theoretically analyzed at the density functional theory level by computing the absorption arising from the self-energy of the IR-active vibrational modes. The characteristics of the two-phonon OH stretching continuum between 7300 and 7400 cm−1 and of the combination bands between 4000 and 4800 cm−1 are related to the specificities of the one-phonon and two-phonon densities of states of the three minerals." @default.
- W4311494562 created "2022-12-26" @default.
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- W4311494562 date "2022-12-14" @default.
- W4311494562 modified "2023-10-18" @default.
- W4311494562 title "Molecular overtones and two-phonon combination bands in the near-infrared spectra of talc, brucite and lizardite" @default.
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- W4311494562 doi "https://doi.org/10.5194/ejm-34-627-2022" @default.
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