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- W4311581386 endingPage "465" @default.
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- W4311581386 abstract "The water-mediated tosylation of alkenes with tosyl cyanide was discovered. Experimental investigations revealed that the reaction was initiated by the in situ formation of sulfinyl sulfone in the presence of water. The sulfinyl sulfone species decomposed to a sulfonyl radical and a sulfinyl radical through homolytic fission. The vinyl sulfone was afforded via sequential addition of the alkene to the sulfonyl radical and the sulfinyl radical, followed by β-elimination of a sulfinyl moiety." @default.
- W4311581386 created "2022-12-27" @default.
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- W4311581386 date "2023-01-01" @default.
- W4311581386 modified "2023-10-17" @default.
- W4311581386 title "Water-mediated radical C–H tosylation of alkenes with tosyl cyanide" @default.
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- W4311581386 doi "https://doi.org/10.1039/d2cc06101e" @default.
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