Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311628029> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W4311628029 endingPage "8563" @default.
- W4311628029 startingPage "8563" @default.
- W4311628029 abstract "The specific features of the siloxane bond unify the compounds based on it into a class with its own chemistry and unique combinations of chemical and physical properties. An illustration of their chemical peculiarity is the behavior of 1,3-bis(2-aminoethylaminomethyl)tetramethyldisiloxane (AEAMDS) in the reaction with carbonyl compounds and metal salts, by which we obtain the metal complexes of the corresponding Schiff bases formed in situ. Depending on the reaction conditions, the fragmentation of this compound takes place at the siloxane bond, but, in most cases, it is in the organic moieties in the β position with respect to the silicon atom. The main compounds that were formed based on the moieties resulting from the splitting of this diamine were isolated and characterized from a structural point of view. Depending on the presence or not of the metal salt in the reaction mixture, these are metal complexes with organic ligands (either dangling or not dangling silanol tails), or organic compounds. Through theoretical calculations, electrons that appear in the structure of the siloxane bond in different contexts and that lead to such fragmentations have been assessed." @default.
- W4311628029 created "2022-12-27" @default.
- W4311628029 creator A5016995699 @default.
- W4311628029 creator A5022717267 @default.
- W4311628029 creator A5026258222 @default.
- W4311628029 creator A5032486444 @default.
- W4311628029 creator A5050166245 @default.
- W4311628029 creator A5061103517 @default.
- W4311628029 creator A5088707155 @default.
- W4311628029 date "2022-12-05" @default.
- W4311628029 modified "2023-09-26" @default.
- W4311628029 title "Some Theoretical and Experimental Evidence for Particularities of the Siloxane Bond" @default.
- W4311628029 cites W1982897362 @default.
- W4311628029 cites W1983547841 @default.
- W4311628029 cites W1988588086 @default.
- W4311628029 cites W2006974554 @default.
- W4311628029 cites W2047360340 @default.
- W4311628029 cites W2059205366 @default.
- W4311628029 cites W2131350133 @default.
- W4311628029 cites W2132525235 @default.
- W4311628029 cites W2335866067 @default.
- W4311628029 cites W2750709526 @default.
- W4311628029 cites W3188423198 @default.
- W4311628029 cites W3203225173 @default.
- W4311628029 doi "https://doi.org/10.3390/molecules27238563" @default.
- W4311628029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36500656" @default.
- W4311628029 hasPublicationYear "2022" @default.
- W4311628029 type Work @default.
- W4311628029 citedByCount "0" @default.
- W4311628029 crossrefType "journal-article" @default.
- W4311628029 hasAuthorship W4311628029A5016995699 @default.
- W4311628029 hasAuthorship W4311628029A5022717267 @default.
- W4311628029 hasAuthorship W4311628029A5026258222 @default.
- W4311628029 hasAuthorship W4311628029A5032486444 @default.
- W4311628029 hasAuthorship W4311628029A5050166245 @default.
- W4311628029 hasAuthorship W4311628029A5061103517 @default.
- W4311628029 hasAuthorship W4311628029A5088707155 @default.
- W4311628029 hasBestOaLocation W43116280291 @default.
- W4311628029 hasConcept C147597530 @default.
- W4311628029 hasConcept C161790260 @default.
- W4311628029 hasConcept C178213299 @default.
- W4311628029 hasConcept C178790620 @default.
- W4311628029 hasConcept C185592680 @default.
- W4311628029 hasConcept C188027245 @default.
- W4311628029 hasConcept C2776139660 @default.
- W4311628029 hasConcept C2776371256 @default.
- W4311628029 hasConcept C2777581007 @default.
- W4311628029 hasConcept C32424582 @default.
- W4311628029 hasConcept C512968161 @default.
- W4311628029 hasConcept C521977710 @default.
- W4311628029 hasConcept C544153396 @default.
- W4311628029 hasConceptScore W4311628029C147597530 @default.
- W4311628029 hasConceptScore W4311628029C161790260 @default.
- W4311628029 hasConceptScore W4311628029C178213299 @default.
- W4311628029 hasConceptScore W4311628029C178790620 @default.
- W4311628029 hasConceptScore W4311628029C185592680 @default.
- W4311628029 hasConceptScore W4311628029C188027245 @default.
- W4311628029 hasConceptScore W4311628029C2776139660 @default.
- W4311628029 hasConceptScore W4311628029C2776371256 @default.
- W4311628029 hasConceptScore W4311628029C2777581007 @default.
- W4311628029 hasConceptScore W4311628029C32424582 @default.
- W4311628029 hasConceptScore W4311628029C512968161 @default.
- W4311628029 hasConceptScore W4311628029C521977710 @default.
- W4311628029 hasConceptScore W4311628029C544153396 @default.
- W4311628029 hasIssue "23" @default.
- W4311628029 hasLocation W43116280291 @default.
- W4311628029 hasLocation W43116280292 @default.
- W4311628029 hasLocation W43116280293 @default.
- W4311628029 hasLocation W43116280294 @default.
- W4311628029 hasOpenAccess W4311628029 @default.
- W4311628029 hasPrimaryLocation W43116280291 @default.
- W4311628029 hasRelatedWork W1979361344 @default.
- W4311628029 hasRelatedWork W2013392010 @default.
- W4311628029 hasRelatedWork W2060852148 @default.
- W4311628029 hasRelatedWork W2126227629 @default.
- W4311628029 hasRelatedWork W2152443264 @default.
- W4311628029 hasRelatedWork W2334685375 @default.
- W4311628029 hasRelatedWork W2914359978 @default.
- W4311628029 hasRelatedWork W3198571145 @default.
- W4311628029 hasRelatedWork W4231738317 @default.
- W4311628029 hasRelatedWork W4311628029 @default.
- W4311628029 hasVolume "27" @default.
- W4311628029 isParatext "false" @default.
- W4311628029 isRetracted "false" @default.
- W4311628029 workType "article" @default.