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• W4311664592 abstract "The gold-catalyzed cyclization/hydroboration of 1,6-enynes offers facile, versatile, and atom-economical one-step access to bicyclo[3.1.0]hexane boranes. This new protocol proceeds in moderate to good yields under mild conditions. Different from bicyclo[3.1.0]hexane borates, these products are stable in air and during chromatography. Moreover, the borane moiety of the products can readily undergo a diverse array of transformations. The kinetic isotope effect experiment indicates that the hydrogen-transfer step is a fast process, which is not involved in the rate-limiting step." @default.
• W4311664592 created "2022-12-27" @default.
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• W4311664592 date "2022-12-16" @default.
• W4311664592 modified "2023-10-16" @default.
• W4311664592 title "Gold-Catalyzed Cyclization/Hydroboration of 1,6-Enynes: Synthesis of Bicyclo[3.1.0]hexane Boranes" @default.
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• W4311664592 doi "https://doi.org/10.1021/acs.orglett.2c03812" @default.
• W4311664592 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36524751" @default.
• W4311664592 hasPublicationYear "2022" @default.
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