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- W4311683764 abstract "Asymmetric catalytic transformations of N-unprotected cyclic carboxyimides such as succinimides, hydantoins, oxazolidinediones, and glitazones, is a powerful way of directly accessing variety of biologically valuable chiral compounds. Herein, a bis(trichlorosilyl) nucleophilic intermediate formed from cyclic carboxyimides was reacted with aldehydes via (S)-SEGPHOS dioxide (SEGPHOSO), proceeding the aldol reaction in highly enantioselective fashion through a cyclic transition state. Furthermore, N-unprotected carboxyimides were chemoselectively activated, even in the presence of N-alkylated carboxyimides, to undergo stereoselective and chemoselective aldol reactions via in situ silicon tetrachloride activation. The functionalized cyclic carboxyimides is readily derived to the several synthetic units derivatization to various chiral building blocks without unnecessary protection/deprotection steps." @default.
- W4311683764 created "2022-12-28" @default.
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- W4311683764 date "2023-02-10" @default.
- W4311683764 modified "2023-10-16" @default.
- W4311683764 title "Enantioselective and Chemoselective Phosphine Oxide‐catalyzed Aldol Reactions of <i>N</i> ‐Unprotected Cyclic Carboxyimides" @default.
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- W4311683764 doi "https://doi.org/10.1002/chem.202203506" @default.
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