FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311686083> ?p ?o ?g. }

• W4311686083 endingPage "381" @default.
• W4311686083 startingPage "375" @default.
• W4311686083 abstract "We report an efficient semihydrogenation of terminal alkynes with H2, catalyzed by a modified, tetramethylated PNP pincer Fe hydride complex. The reactivity contrasts with an analogous classical PNP Fe hydride complex containing CH2 arms, which catalyzes predominantly terminal alkyne dimerization even in the presence of H2, and with an N-Me arm PNP Fe complex, which is known to cause overreduction to alkanes and requires the presence of a trimethylsilyl protective group. Such straightforward PNP ligand modification is a convenient tool that switches reactivity and leads to selective alkene formation, with no dimerization side products observed and only a minor contribution from overreduction." @default.
• W4311686083 created "2022-12-28" @default.
• W4311686083 creator A5029544797 @default.
• W4311686083 creator A5039911719 @default.
• W4311686083 creator A5059205850 @default.
• W4311686083 creator A5061534298 @default.
• W4311686083 creator A5075731581 @default.
• W4311686083 date "2022-12-16" @default.
• W4311686083 modified "2023-10-11" @default.
• W4311686083 title "Efficient Fe-Catalyzed Terminal Alkyne Semihydrogenation by H₂: Selectivity Control via a Bulky PNP Pincer Ligand" @default.
• W4311686083 cites W1970800627 @default.
• W4311686083 cites W1978509358 @default.
• W4311686083 cites W1988091937 @default.
• W4311686083 cites W2002501218 @default.
• W4311686083 cites W2011215428 @default.
• W4311686083 cites W2043052345 @default.
• W4311686083 cites W2046269013 @default.
• W4311686083 cites W2051594489 @default.
• W4311686083 cites W2128212524 @default.
• W4311686083 cites W2150195378 @default.
• W4311686083 cites W2199955807 @default.
• W4311686083 cites W2235206970 @default.
• W4311686083 cites W2316261853 @default.
• W4311686083 cites W2335973984 @default.
• W4311686083 cites W2529489495 @default.
• W4311686083 cites W2578157441 @default.
• W4311686083 cites W2595043795 @default.
• W4311686083 cites W2904503380 @default.
• W4311686083 cites W2922318564 @default.
• W4311686083 cites W2969203389 @default.
• W4311686083 cites W2979568257 @default.
• W4311686083 cites W2983970986 @default.
• W4311686083 cites W2995195771 @default.
• W4311686083 cites W2996505981 @default.
• W4311686083 cites W2999909001 @default.
• W4311686083 cites W3007604147 @default.
• W4311686083 cites W3136902952 @default.
• W4311686083 cites W3138856760 @default.
• W4311686083 cites W3208051642 @default.
• W4311686083 cites W3208590342 @default.
• W4311686083 cites W4200351415 @default.
• W4311686083 cites W4214701883 @default.
• W4311686083 cites W4220809585 @default.
• W4311686083 doi "https://doi.org/10.1021/acscatal.2c04274" @default.
• W4311686083 hasPublicationYear "2022" @default.
• W4311686083 type Work @default.
• W4311686083 citedByCount "2" @default.
• W4311686083 countsByYear W43116860832023 @default.
• W4311686083 crossrefType "journal-article" @default.
• W4311686083 hasAuthorship W4311686083A5029544797 @default.
• W4311686083 hasAuthorship W4311686083A5039911719 @default.
• W4311686083 hasAuthorship W4311686083A5059205850 @default.
• W4311686083 hasAuthorship W4311686083A5061534298 @default.
• W4311686083 hasAuthorship W4311686083A5075731581 @default.
• W4311686083 hasConcept C116569031 @default.
• W4311686083 hasConcept C118792377 @default.
• W4311686083 hasConcept C142724271 @default.
• W4311686083 hasConcept C155647269 @default.
• W4311686083 hasConcept C161790260 @default.
• W4311686083 hasConcept C170493617 @default.
• W4311686083 hasConcept C178790620 @default.
• W4311686083 hasConcept C185592680 @default.
• W4311686083 hasConcept C204787440 @default.
• W4311686083 hasConcept C21951064 @default.
• W4311686083 hasConcept C2776254738 @default.
• W4311686083 hasConcept C2776910235 @default.
• W4311686083 hasConcept C2777000832 @default.
• W4311686083 hasConcept C2777961443 @default.
• W4311686083 hasConcept C2778468751 @default.
• W4311686083 hasConcept C2779012754 @default.
• W4311686083 hasConcept C512968161 @default.
• W4311686083 hasConcept C55493867 @default.
• W4311686083 hasConcept C71240020 @default.
• W4311686083 hasConcept C71924100 @default.
• W4311686083 hasConcept C91819851 @default.
• W4311686083 hasConceptScore W4311686083C116569031 @default.
• W4311686083 hasConceptScore W4311686083C118792377 @default.
• W4311686083 hasConceptScore W4311686083C142724271 @default.
• W4311686083 hasConceptScore W4311686083C155647269 @default.
• W4311686083 hasConceptScore W4311686083C161790260 @default.
• W4311686083 hasConceptScore W4311686083C170493617 @default.
• W4311686083 hasConceptScore W4311686083C178790620 @default.
• W4311686083 hasConceptScore W4311686083C185592680 @default.
• W4311686083 hasConceptScore W4311686083C204787440 @default.
• W4311686083 hasConceptScore W4311686083C21951064 @default.
• W4311686083 hasConceptScore W4311686083C2776254738 @default.
• W4311686083 hasConceptScore W4311686083C2776910235 @default.
• W4311686083 hasConceptScore W4311686083C2777000832 @default.
• W4311686083 hasConceptScore W4311686083C2777961443 @default.
• W4311686083 hasConceptScore W4311686083C2778468751 @default.
• W4311686083 hasConceptScore W4311686083C2779012754 @default.
• W4311686083 hasConceptScore W4311686083C512968161 @default.
• W4311686083 hasConceptScore W4311686083C55493867 @default.
• W4311686083 hasConceptScore W4311686083C71240020 @default.
• W4311686083 hasConceptScore W4311686083C71924100 @default.
• W4311686083 hasConceptScore W4311686083C91819851 @default.
• W4311686083 hasFunder F4320322443 @default.
• W4311686083 hasIssue "1" @default.

• next