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• W4311700829 abstract "Abstract We report the direct evidence of valence fluctuation in the thermoelectric material Yb 3 Si 5 by using synchrotron X-ray photoemission spectroscopy. The Yb 3 d core level photoemission spectrum of a Yb 3 Si 5 single crystal shows clear separation of the Yb 2+ peak and Yb 3+ multiplet peaks. From the spectral weight of each component, the mean valence of Yb ions is estimated to be +2.67 at 20 K. Furthermore, a Kondo resonance peak just below the Fermi energy is also observed by high-resolution soft X-ray photoemission spectroscopy, suggesting the valence fluctuating state in Yb 3 Si 5 ." @default.
• W4311700829 created "2022-12-28" @default.
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• W4311700829 date "2022-12-30" @default.
• W4311700829 modified "2023-10-14" @default.
• W4311700829 title "Valence fluctuation in Yb₃Si₅ probed by synchrotron X-ray photoemission spectroscopy" @default.
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• W4311700829 doi "https://doi.org/10.35848/1347-4065/aca911" @default.
• W4311700829 hasPublicationYear "2022" @default.
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