FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4311752154> ?p ?o ?g. }

• W4311752154 endingPage "68" @default.
• W4311752154 startingPage "1" @default.
• W4311752154 abstract "The notion of asymmetrical Hydrogen Bond (O:H-O) Cooperativity and Polarizability (HBCP) has enabled exploration of the core physics behind irregularities of water and ice, particularly, the evolution of mass density, phase stability, energy exchange, and their transition velocity under perturbation. We humbly share the initiatives of the quasisolidity presented between Liquid and Ice, the supersolidity pertained to polarization by electrification or molecular undercoordination, and the H↔H and O:⇔:O repulsivity owing to the respective injection of excessive protons and lone pairs to the liquid by solvation. The O—O repulsivity forms the key that drives the O:H-O bond to cooperatively relax its segmental length, cohesive energy, vibration frequency, and specific heat upon perturbation, which establishes an efficient set of parameters to feature the bonding and electronic dynamics in the frequency–space–time domains. An interplay of the segmental specific heats defines the mass densities, phase boundaries, and the exotic quasisolid (QS) phase that exhibits negative thermal expansivity through H-O contracting less than the scale of O:H expansion upon cooling. However, the H-O bond undergoes cooling elongation in the Liquid and the Ice-I phase and remains silent in the XI phase. H-O bond absorbs energy by contraction and does it inverse at expansion. The O:H nonbond always relaxes more than the H-O bond does in contrasting direction. Mechanical compression symmetrizes the O:H-O segmental length associated with polarization, which disperses inwardly the QS phase boundary to lower the Tm for melting but raise the temperature TN for ice nucleation and the TV for evaporation, resulting in the phenomena of ice regelation and instant-ice formation. Polarization, however, has the contrast effect to compression on the hydrogen bond relaxation and phase transition. The polarization converts the pristine water into the gel-like, hydrophobic, and viscoelastic supersolid which is less-dense and thermally more diffusive and stable, entitling surface premelting, superheating at Tm, and supercooling at TN and TV. Polarization enhances the dielectrics of water and widens the bandgap of ice. The supersolidity ensures the 120 K superelasticity of ice microfibers and the 330 K stability of the electrified water bridge crossing the rims of infilled containers. The high elasticity of the softer O:H nonbond and the interface electrostatic repulsivity secure the slipperiness of ice and the superfluidity of water traveling in fine channels. The skin supersolidity and the O:H-O bond memorability uniquely foster the Mpemba effect — warm water cools more quickly. The H↔H or O:⇔:O repulsivity modifies the bonding network and solution properties through solvent H-O bond elongation, solute H-O bond contraction, and polarization. The HBCP premise has thus correlated the irregularity of water and ice to the O:H-O bonding and electronic dynamics under perturbation. Further extension of the HBCP to aqueous and molecular assemblies involved with electron lone pairs and coupling interactions could be even more fascinating and profoundly promising." @default.
• W4311752154 created "2022-12-28" @default.
• W4311752154 creator A5070538645 @default.
• W4311752154 creator A5075523709 @default.
• W4311752154 creator A5081369135 @default.
• W4311752154 creator A5083679415 @default.
• W4311752154 creator A5090187076 @default.
• W4311752154 date "2023-02-01" @default.
• W4311752154 modified "2023-10-18" @default.
• W4311752154 title "The physics behind water irregularity" @default.
• W4311752154 cites W1485423384 @default.
• W4311752154 cites W1546233314 @default.
• W4311752154 cites W1564681792 @default.
• W4311752154 cites W1605936672 @default.
• W4311752154 cites W1618744808 @default.
• W4311752154 cites W1670329995 @default.
• W4311752154 cites W1743791033 @default.
• W4311752154 cites W1831157241 @default.
• W4311752154 cites W1889401123 @default.
• W4311752154 cites W1963756055 @default.
• W4311752154 cites W1967023939 @default.
• W4311752154 cites W1967177165 @default.
• W4311752154 cites W1967927417 @default.
• W4311752154 cites W1968671164 @default.
• W4311752154 cites W1969930445 @default.
• W4311752154 cites W1970038391 @default.
• W4311752154 cites W1970161259 @default.
• W4311752154 cites W1971596417 @default.
• W4311752154 cites W1974397369 @default.
• W4311752154 cites W1975727760 @default.
• W4311752154 cites W1976081321 @default.
• W4311752154 cites W1976345543 @default.
• W4311752154 cites W1977741966 @default.
• W4311752154 cites W1978066323 @default.
• W4311752154 cites W1978087790 @default.
• W4311752154 cites W1979718259 @default.
• W4311752154 cites W1982264278 @default.
• W4311752154 cites W1983922143 @default.
• W4311752154 cites W1984064219 @default.
• W4311752154 cites W1984403140 @default.
• W4311752154 cites W1986813980 @default.
• W4311752154 cites W1990807946 @default.
• W4311752154 cites W1993869400 @default.
• W4311752154 cites W1994067232 @default.
• W4311752154 cites W1994316904 @default.
• W4311752154 cites W1994470089 @default.
• W4311752154 cites W1996819251 @default.
• W4311752154 cites W1996854030 @default.
• W4311752154 cites W1997282930 @default.
• W4311752154 cites W1998358855 @default.
• W4311752154 cites W1999251332 @default.
• W4311752154 cites W2000196463 @default.
• W4311752154 cites W2000831975 @default.
• W4311752154 cites W2001822240 @default.
• W4311752154 cites W2004096590 @default.
• W4311752154 cites W2005044961 @default.
• W4311752154 cites W2005247476 @default.
• W4311752154 cites W2006581268 @default.
• W4311752154 cites W2007709718 @default.
• W4311752154 cites W2009054382 @default.
• W4311752154 cites W2011619853 @default.
• W4311752154 cites W2012122997 @default.
• W4311752154 cites W2012165941 @default.
• W4311752154 cites W2012410670 @default.
• W4311752154 cites W2012618050 @default.
• W4311752154 cites W2013313420 @default.
• W4311752154 cites W2014337825 @default.
• W4311752154 cites W2014418086 @default.
• W4311752154 cites W2017874613 @default.
• W4311752154 cites W2019587771 @default.
• W4311752154 cites W2022153579 @default.
• W4311752154 cites W2022754859 @default.
• W4311752154 cites W2022758039 @default.
• W4311752154 cites W2022807291 @default.
• W4311752154 cites W2023192572 @default.
• W4311752154 cites W2023456894 @default.
• W4311752154 cites W2026761805 @default.
• W4311752154 cites W2027009663 @default.
• W4311752154 cites W2029279921 @default.
• W4311752154 cites W2031914212 @default.
• W4311752154 cites W2033066066 @default.
• W4311752154 cites W2033807225 @default.
• W4311752154 cites W2034381137 @default.
• W4311752154 cites W2035375384 @default.
• W4311752154 cites W2036942146 @default.
• W4311752154 cites W2037236236 @default.
• W4311752154 cites W2039296412 @default.
• W4311752154 cites W2040277608 @default.
• W4311752154 cites W2040845727 @default.
• W4311752154 cites W2041052169 @default.
• W4311752154 cites W2041182697 @default.
• W4311752154 cites W2041427028 @default.
• W4311752154 cites W2044066443 @default.
• W4311752154 cites W2045566664 @default.
• W4311752154 cites W2046657843 @default.
• W4311752154 cites W2049603070 @default.
• W4311752154 cites W2049613735 @default.
• W4311752154 cites W2051604968 @default.

• next